H M X E ~ O P O ~ ~ CTKOMC~Y ~ P C T B E H HT~EI ~ XHM~ECKM~ YHMBEPCMTET M ~ T O ~ U ~yKa3aHUR ~ C K U K IlpaKTHVeCKHM ~ 3aHSlTURM no K y p C y o6qeii X H M U H W F I XHMHCleCKHX H HeXHMUCleCKHX C f l e ~ H a n b ~ ~ C ~ e ~ KOPPO~WR - m n p o q e c c c a ~ o n p o ~ ~ p~a 3~p y ol u er~ no. n m e r a n n o s r r p n HX XHMH'leCKOM. 3 n e K l p O X H M H q e C K O M UJIH ~ H O W I M H ~ ~ C K OBM ~ ~ U M O A ~ ~ ~ CCT Y BaHC H nillaMH o l c p y m a m u e f i cpenu K O P P O ~ H O H H ~ npoueccu I~ ~ O C R T C RK p p w o w c n n m b ~ o ~ o c c r a ~ o s m b p~ e a ~~u xw i i , B KOTOP~IX~ e m m ncerna R B R R ~ R~ocmosHTeneM,a qacmqbl 0 ~ p y x a I o ~ l e i iCpenbl ~ b l c r y n a w ~B ponn o w c n m . Hm6onee paC1rpOCTpaHeHHblM OKUCnHlWleM RBJlAlXCR iWMO~f&pHbIfi KUCnOpoA. Pa3JIHqaIUT X&iMHqeCK)'IO, 3JlekTpOXUMH'leCKYK) H ~ H O X H M H ~ ~ C K KOPpCl3HK). ~IO X n m ~ q e c l c a u K O P P O ~ H R ~ e ~ a n n- om ~ pmpyuleeae ~ e m m o anon n e i i c ~ ~ u e m a r p e c c n m b r x ~ O nBp w B ~ I C O K H X TeMnepaTypax ( r m o ~ m KOPPO~HR), a Tame papyueliue M ~ O B pacTBopax B ~e3nelrrponn~os, r.e. B Henpoeomunx cpenax. ~ H O X H M W ~ C K ~ R KOPPO3HR XCH3HeAeJTIZJlbHOCTbK) Bbl3blBamR Pa3JIlll(HblX I T H ~ a ~ e J l b H 0 f i CpCnbl. E W O K O P ~0~6~b lW q ~R0 COqeTaeTCR C n p Y r H M H B U m H K O P P 0 3 H H . ,&In ee pa3BHTHJT ~ a w 6 o n e ~e J I ~ I ' O ~ ~ H J Tn0qBbl T H ~ I O n p e n e n e H H o r o cocrasa, 3 a c ~ o R H b l eBOAbl H HeKoTOpble opratinrecKwe n p o n y n b l . 3 n e ~ ~ p o x ~ r n n KOPPOPHR ~ e c ~ a ~ B c r p e q a e T C n S u e ~ p y r n xB H ~ O BK O ~ ~ O ~ U O H H O ~ O p a p y m e H n n H nau6onee onacHa rn Merannos. Ona M O X ~npoTeKa-rb B rmo~oii a-ruocaepe, Korna H a nosepxtiocra vaanna BOSMOXH~ KoHneHcaqnR Bnarn ( ~ T M O C ~ ~ K~ OHP ~~ ~R ~ H RB ) l,l O q B e ( ~ O V B ~ H H ~KOPPO~HR), UI B ~ 0 J l e H 0 f i H w H 0 f i Bone. B 3 a ~ w c u ~ o c r OT w xapampa p a 3 p y l u e ~ ~ npn i i 3 n e l r r p o m ~ ~ r e c ~ oKOPPOSHH fi PaZnH~iWOT CrUlOUlHVtO KODD03HK). 3aXBaTbtBaIoqYIO BCK) nOBepXHOCTb MeTaJlna U M W K P O O p ~ a I ~ U 3 M O B , HCnOnb3yIOll(UX MeTaRn B KaSeCTBe 3JIEKTIQXMMM~ECKASt KOPPOSMX ~ J I ~ K T P O X H M U ~ ~ CKOPp03HM KO~ MeTaJlJlOB M O R e T 6 b l ~ b paCTB0peHHblfi B Bone KMCJIOpOfl. B 3TOM Cnyqae rOBOpRT, qT73 K O P P 0 3 H R npOTeKaeT C ~ n c n o p o n ~ o~i ei n o n n p u s a u n e i i : O2 t 4 1 p + 4e 2 1 1 ~ 0 ( pH*) EO=+ 1 , 2 2 8 B O2 t 21i20 + 4e -- 4 0 K (pH=7) E L +0,8 1 B O2 t 2 ti20 + 4e 4 0 K @H=14) E0= +0,40 1 B ' f a ~ n o6pa30~, ~ B ~ n c n o i i cpene noneepraTL.cn ~ o p p o s w u c ~ncnopon~oii ~efl0JIJTpH~~ueii MOryT MeTaJWhl, C T a H n a p ~ ~ b l f3JlelClp0flHblii i nOTeHqHaJl KOToPblX OpnuaTenbHee 4 1 , 2 3 B, B t ~ e E i r p a r t b ~ o t i ' + o , 8 1 u q e n o s ~ o f -i o-rpkqarenb~eet 0,4B. A K T W B H ~MC'I'aJIJlbl I~ B K H C J ~ O ~C~p e R e KOppOnHpyIOT C BO,~OPO.L~HO~~ f l e n o d l n ~ w 3 a l l u e k ,T e B KalleCTBC OKnCnkiTenR BMCTynaIOT ~ B 0 6 0 n ~ bHOHbl le BOllOPOlla 2H' t 2e (pH 4) EO- 0 R 3 OKHC~UT~JI~ IIPH M - - HawGonee rrpocmfi MoDenbo ~0pp03no~ti01.0 3neKrpOXWMHrt2CKOMy MeXaliW3My, RLlJUIelCH MOA€?Jlb npoqecca, 3ne~eH-m. BO~HHKHOB~HH KaTO,L(HblX ~ W a H 0 A H M X Y'iaCTKOB CBH3aHO c x n ~ n r e c ~ o fH i MeXaHWWXKHMW Tl?MnepaTypHblM MHOrHMW ,L(PYrWMW &%C~QP~MW. KOHTaKI'OM P ~ C C M O T ~ W HeKOTOpble M noflcpxtlocru; KOPPO~HOHHO~ HeOAHOpOAHOcTbto nOBepXHOcTH; no H a ilOBePXHOC1.W M C T a n n a r e o ~ e q - m r e c ~ o i ir i e o A H o p o ~ H m b m HallpRXeHHRMH; rpaWeHlDM wuy11lc1.0 KOppO3HOHHOrO r d l b B a H H ' l C ~ K O l ' 0 C Apyl'WMH H 3 3THX CpeAhl; MtT&IUIaMU W ~ $ B K ~ o ~ O&nee B noapo6~0. XHMHW~CK~H HeOnHOpOnHOCTb KOP~O~HH yrnepo~wcroii crann AJIR Hnxe n p W B e n e H b l CXeMbl cpen, B KOTOP~IX n a c c n B H b i M n ~ a p 6 w ~X eaJ l e 3 a (Fe3C). IlOBepXHOCTH. pavlurnbrx (K~TO~H~IMH Y'laCTKaMH ) RBJlRfOTCR 3 e p H a B n ~ i w l ~ r ll ei e o n l r u p o a n o c r i i CClCl2Ba Cpellbl Moxel cocrasa K O ~ ~ O ~ H O H Icpewr. I O ~ ~ Heont~opon~~ocrb K 06pa30~a~wtoMWKp0I';LllbBaHOllaP IJdXC H a npWBonwrb nOBCpxllOCTW OflHOrO W T o r 0 X C M C l T l n n a . ~ P W M C P O MM O X C T CJIYXWTb KbPP03WR MeTLZnJla n0n ~all!lefi BOnbl paC'rBOpeHHOl'0 ' r a ~ KaK KWCnOpOna, ~aIlJlefiOKa3blBaeTCH Gonee qeM IlOBepXHOCTHble BHylQeHHWe, CnOW BOabl nOBf3pXHOCrb COAepXaT 60~lb~le M e m M a B UeHTpe llofl BWHBHO~~ ( ~ H O A H ~yqaCT0~). I ~ ~ ~ ~ O C BblCblXaHWR J I ~ KaMW B ~ C H ' l p e~ C r a J l J l W q e ~ IlJIaCTWHKM ~~fi nORBJureTCR n O B O J I b H 0 my60~0erUlTHO PXaBL1l.LHbl. Ta~we n p o q c c c t . 1 ~ a u h n e eracro ~ a 6 n m n a l o ~npw c ~ a ~ ~ o c a e p ~ wo f ~i O ~ B ~ H KOpP03WH. B O ~ U ~ CCMJ l y q a e HeOAHOpoAHOCTb COCTaBa C p e A b l n p U B 0 , l W T K H e p a B e H C T B y 3JleKlpOflHblX l I O l Z H 4 i a J l O B cnoco6cr~yerO H a pZ33JlW'IHblX Y ~ a C T K a X IlOBepXHOCTH M W l a , H O ~ LiTO U ~ ~ ~ ~ O B ~MH WK H pH O E, U I b B a H O n a p . Mexannrecicne H a f l p R m e H H U . K O P P O ~ W O H HM~WI ~K p O ~ b B a H O I I a p b l M O r p npW A ~ ~ ~ C T B WBHeIlIHkiX W W B H Y W H H W X MeXaHWIeCKHX H ~ I I P I I X ~ H W ~ ~ ( ~ a n p w ~ eocra-roqtibre p, H a n p R X e n w R nocne c ~ a p ~ wKOPPO~HR ). npw A ~ ~ C T B WBHeLuHWX H B03HWKaTb I4 BHYTpeHHWX- ~ a f l p R X e ~ &IIpWBOAMT K M e X K p U C T a J l J l u T H O M y P a C T P e C K u B a H H l o KnW T a K ~ a 3 b l B a e M o f i" H O X ~ B O ~ K ~ "O P P 0 3 H H . KMHETMKA KOPPO3MOHHblX IIPOUECCOB I 7 p a K r U q e c K m n e R X n b H 0 C T b A a e T MHOrO IlpwMePOB T O ~ O , KaK M W b l KOppOnWpyJOT CKOpOCTb KOPP03HM 6onee aKTWBHble Hanpw~ep, 3 H a W f T e J I b H O M e W e H H e , Y e M M e H e aKTHBH6le. &JIIOMNHWII B ~ T M O C @ ~ P H ~YCJIOBHIIX ~X 3Ha'iHTeJIbHO MeHbllle CKOpOCTH KOppO3HW X C S l e 3 a , XOTR c ~ a ~ ~ a p r r t b 3l Jf Ii e K T p o ~ b l f i I I O T e H U U m 2lJltoMHHWR HaMHoro Gonee olpwqa-reneti. 3 s o ~$ a ~ rI - o ~ o p wo~ TOM, TepMO.L(WHaMWqeCKWX WHWW qecwe 1ra~6onee B aranopb~, K ~ HM ~ u3 I rTo n o M w M o BJIWRHWR H ~ O ~ X O A H M OYqWTblBaTb ~~KTOPOB H a IlPOUeCCbl KOPPO3MH K O T O ~ ~ I Xc n e A y e T H oTHecT1f c f l 0 ~ 0 6 ~ 0 MeTaJIJIOB ~ b IlepeXOflHTb B IlaCCWBHOe COCTQRHWC. I I ~ o ~ ~IlaCCWBaUWW cc TOHKWX (no HCCKOIlbKWX MeTaJlJlOB CBR3aH C 0 6 p a 3 0 ~ a ~H~a eHX ~ IlOBepXHOCTW MOJIeKYflRpHblX C ~ O ~ B N I)e H O K MaJlOPaCTBOPHMMX ~ O ~ A W H ~ H H ~ ~ - OKCW,4OB, rUnpOKCWAOB, conefi. C K O ~ O C T ~K O P P 0 3 H H B 3 ~ a q W ~ e J l b ~ 0CTefleHW h 3aBHCHT BOCCTaHOBJICHMR VaCTtiU OKWCJIUTeJlR H a KaTOAHblX f l a C T K a X cnyqae K W OT CKOPOCTW flOBepXHOCTM M W Z r L n a . O ~ ~ O ~c HK H C J I O ~ O I ~ H1lenonnpw3aqueii O~~ ~aw6onec~ ~ M C J I J ~ H H ~ I M W B 6blcrpee, KOTOpOe qeM MeHbure nepeHarrpRmeHne nHMHTHPYaCR H a n p n ~ e p ,UIIHK, CKOPOiXbH) peaann PeaWHH sslneneHuR BOCCTaHOLUIeHWR KaK aKWi6Hblfi MHaJlJI, TePMOAHHaMH'IeCKH sonopona (q~2,B), HOHOB BOAOpOila. H ~ Y C T O ~ ~ ' ~6W KHCJll,lX R C p e A a X . O m l a K 0 O l l O q e H b M e m e H H O BblTC?CHReT B O A O p O n H 3 P a C r B O P O B KWCJIOT, l a K K a K CKOPOCTb UOCCTallOBJleHWR B O A O P O A a H a H e M O q C H b M i l l l a peaKuHH). B K O H K 3 K X C MeAbtO, 3l{arHTeJ16HO 6blc-rpce, (6onr,uroe llep~HallpHXCliMC H a K O T O P O ~ ~B O C C T d H O B J l e H H e B O n O p O n a IlpO-leKaCT U H H K p a 3 J l a ~ a e TKHCJIOTbI O Y e H b a K W i B H O ; q'I.0 OTMCq;1CrCH 110 3 H a ' ~ H T e J l b l l O M YB b l U e J e l i H K ) B O A O P O A a . - @AK'TOl'bl, BJIMIIIO~MEIiA CKOI'OC'rL ICOPPO3MM MIZ71'AJ1J1013 BJ~HRH pliH pamsopa. ~ llaccnsaqn~M e T a m i a q a q e 6cer.o c s x - l a ~ l a c 0 6 p a s o s a t 1 w c h * H a er0 I l O B C p X H O C T H M a J l O p a C T B O p H M b l X n J I e l i O K O K C H a O B H rH:!pOKCHjlOB. I'CBKUMR c p e n h l , T.C. pti pacreopa, snnxm H a xapawcp p a c r n o p n M o c r n 31ns IIJICIIOK. I3 TOM C n y Y a e , e C J l H O l i H o ~ J I ~ ~ & ~O O C HTO B H b l M H C B O ~ C T B B M H , 3 a L U H T H O e L \ ~ G c ~ . D HHX ~ ~ Y A C TB 6onbmeii cTeneHn npoasnmbcn B wenowtblx cpenax, rne pacruopmocrt, w n x hleHl>lUe. ~ ~ c J I H O K C H n H b l e ( l . H ~ p 0 ~ ~ l l f l ~ b Ill eJ I)C l i K H MCTiLIIJIOB 06~la)!il~).1. C B O ~ C T B ~ M H ,K O P P 0 3 H O H H a R Y C T O ~ ~ ( H B O C T ~MeTiFlLnOB I l p O r t B J R T b C R €3 K H C n b l X C p e A a X . B COOTBeTCTBHH ~YACTB nncHoK KHCJlO.rHblML1 G O J I ~ I U C I C1.CIICtIL1 ~ C 3 T U M B C e M C T X h l b l MOXillO p a 3 f l e n W r b pna r p y r l n : 1 ) M e T Z O J I b l , ~ e ) ~ C l ' o f i ' 4 H B b l e 6 KHCJIblX, H O K O P P ~ ~ H ~ H H O C T O ~ K HH CIl[CJIOY l l b l X c p e s a (Ni,Co,Cd,Mg,Mll,Fe); 2) M C r U I J l b l , K O ~ ~ O ~ U O H H O C T O ~B KKHH~C J l b l X , H O H e ) ' c . I ' o ~ L ( H R ~ ~ c H II(CJIO'IH1~IX p a c 1 . 1 3 o p a x (Ta,Mo, W); 3) M e T a n J I b l , K O P ~ ~ H O H H O ~ O ~B KH eI fIi '~I p i ~ l l b H b l p~a C T H O ( ) a X , H O I ~ e y C l ~ ~ ~ l k t3i U K H C J b l X H I ~ e J I O ' I l i 6 l X C p e n a X (Zn,AI,Sn,Pb,Bi,Re)l Y 3 T H X M e T Z O J l O H 3 a w H T H b l e C!IOIT n M e m a M 4 o r e p ~ b Gi1 xapamp; 4) M W I ~ I , c~opomt.K O P ~ J H WK O T O P ~ I X n p a m n l { e c K n H e 3 a n n c n ~01. pti C p C j l b l (Ag,Au,Pt). C O C ~ H~e fBi ~ p W I b H b l X P a C T B O P O B . C K 0 ~ 0 ~ l . bKOI)PO'%HM M C I . U I J I O B H R O f l H b l X pac-rsopax 3 a B H C H T OT n p n p o n b r pncrsope€rliblx B o o ~ c neulec-ru. 13~1 nw~iwe lia p a C l ' B O p e l i l l 6 l X Relllecl.6 I) pac-ruopnMoc-rb 6 MOmCr FH!lpOJlH:%yWlllUeCR 6 ~ C B~H S ~bI ~C O COJIH H3MCHHIO1' C J I ~ J I ~ K ) I I ~$ Ha lM~ ~r o p d ~ ' i : pl~lp;1CT'I1OpOI% I l o n c p x l i o c r s 1 , l x C O C , ~ ~ I I CuGi H MCT~JIJIR; H 'I.CM C a l b l M t3JIHIIIO.I. H;1 b er0 K O P p 3 H W 1UIeFiKy M a I l O p a C T B O p U M b l X C O ~ ~ I I H ~ HT eHM~ C, a M b i M n a C C U B H p y R er0; 3) H e K O T O p b l e a H H O H b l ( H a I l p U ~ e p MOHbl CI-), a n c o p 6 n p y ~ c b H a n 0 B e p X H o m ~erma,pa3pymato~ O K C U A H ~ H , n n e H K y w Y C K O P ~ T npoqecc KOPPOJHH. Tame r a m n q b l racro ~ a 3 ~ nee nm a c c u s a m p a M n ~oppo3nu. K O M ~ ~ ~ K C O O ~ D ~ ~ .OHBa n~ nHq w H e~ B. pamaope B e q e m s , T a m x K ~ K NH,, CN- H np., c n o c o 6 m ~ y ~ ~0 n6 pxa 3 0 8 i l l l ~ t O KOMIIJIeKCHblX C O ~ A M H ~ H H p~e,3 K O Y B e n U r H B a e T C K O p O C T b K O p p 0 3 W H . H a n p n ~ e p ,Me&, K O ~ ~ O ~ U O H H O ~ C T MeTaJlJt, O ~ W BB ~P ~a C~T ~ BOpe Z I M M U a K a K O p p O n H p y ~C ~ O c r a T O r F i O6 O n b l u 0 ~C K O p C T b t O : 2Cu t O2 + 8NH401i = ~ [ C U ( N H ~ ) ~ ] ( O+H6 H ) ~2 0 Y B ~ S I H V ~ H CHK~O p O C T H KOPPO3HH CBR3dHO C TeM, VTO K O M ~ ~ J I ~ K C O O ~ ~ ~ ~ O B 3a creT cnsnra ero n o - f e H u n a J i a 2+ B O T p H U a T e J 1 6 H y O LTOPOHY. I l a n p u ~ e p~ : ~ c =~+ 0 , 3 3~7 ~:; E~" ~ ~ , , ~ Icu ~ 3 =0,04 ) 4 ~ B. MEl'0Abl3AIl~MTblMETAJUIOB OT KOI'P03MM M e r o f l b l 3 a W M T b l M C E M n O B O T K O p p 0 3 H H M O X H O p a 3 A e I l U T b H a H e C K O n b K O lpynn. y B e n n V u e a e T B o c m d H o u n T e n b i i y t o a t c l n e r i o c ~ bM e T a J m a W H U a T e n e H , .leM llOKpblTURMM 6) f l 0 K H U H a J l OCHOBHOrO M e T m a . 6 y f i U~H H K &nee H X p M , T.C. Hanpw~ep,lUA X e J I e 3 a aHOflHblMH aPX'HBHble M e l a W I b l . y KOTDP~IX n o T e H u w a n 6onee ,D.m xenesa B K a y e c r s e K ~ T O ~ H ~ K a T o J I ~ b l e I I O K ~ ~ I T W H3. r o n o ~ p b l ~ nMn e l m a M n , nonomTeneFI, qeM y noKpblBaeMor0 Memnna. I X ~~OKF)MTH M~O~X H O M C l l O n b 3 O B i l T b H H K e n b H O n O B O . f ! e ~ e T a J l l H V e ~ K ~ . n o ~ p Ibl 1p ~e ~n ~~ .~ a B n R ~ t O0 ~6 0 k W 3 0 n H P Y H ) q H e CnOH KpaCOK, n a K O B , p e 3 M H b 1 , ~ M X T C I~U,l a C T M a C C H A P . 3ro c n e u t i a n b c l o c o 3 n a ~ a e ~ b Hr ea X n ~ n q e c h - w eI I O K ~ ~ I T H I I . e r O XMMHVeCKM C T O ~ ~ K COeACIHCHHH, M ~ c n o c 0 6 ~ b l e H30nHPOBal'b c p e n h r : O K C M J ~ ~(1)0c(l)a.l.hl, I, cynb$a.rbr 2. M ~ T O A ~O CI ,I I U U ~ H H ~ IHCa n0sepxHocn.r Meranna e r O OT 0KpyXaH)Ill~fi w jlp. c r r e q ~ a n b 1 4 o f i0 6 p a 6 0 ~ ~ KO e P P O J H O I I H O ~ ~c p c f i b l . K H H h l OTHOCIlT I I p O U e C C b l H ~ ~ ~ T ~ ~ L I I UO~~~CUC W KH I ~C ,~ O ~ O X H B ~B~B~CHf i R e H, H e W H ~ H ~ U T O ~ O H (3a~ellJllr~eneii) KOpp03UM. KOPPO~UOHHO% CPellLl HeopraHwqecKne, iaK Me'roabi OrpaHMqCH. n HCIlOJlb3YtoTCR KaqeCTBe B CnyVax, H H I ~ W ~ W T O P O BMOI'YT o p r a t i ~ q e c ~ w euemecrsa: nahlc:vlcHtiw KaK C~PHK, KBK a H O J l H Y H ) ' l a K H K ~ l ' I ' O j ~ H YC~T W l H K 3 B O C C l X H O B n e H H R OKMCnWTe.TlR. 1iau6oi1ec ~ c - r o ~o~eiic~ I r auc rn w lel ~ M e x a r l n ? ~ I I C ~ ~ C I I ~ Mn H ~ l ' n 6 n ~ r o p ~O o~~ f ( e .6i h. l ~ h p a r w l n ~ j e ~ i o, n i i a l t o x!)+etcr 06be~ CIIYXtiTL x p o ~ a ~ b a~) o, c $ n b ~ , ~ 0 p ~ ; l n b A e r l i f i . a h l b i l r b l , Y P U I P O I I H H M U P . M H I ' M ~ W T O Ph ~4 O ~ I . p 3aMellJlR7.b PeaKUMKl OKHCJI~III~H hlC'I.;LIUla, KOrAa K O ~ P O ~ M CHB H . ~ Hc ~ I I C ~ ~ G I I M O H ~ H ~~I aM n u ~ I I . H ~ H I . O PIi~ II<~BL'PXlfOl:I I I>tO H C laJI.I;i BOCC'KiHOBJLeHUR 'laCTHq O K H C ~ H W ~ J l . IlPMMEPbI PELLIEHMR 3AAAY UPMMEP 1 . C O C T ~ B CX~eMTV~K O D P 0 3 H O H H O ~ OrCiIIbBaHHl(eCKOT03neMeKra U s a n u ~ o n pealtqnu. ~e nwxrcarouue npu e m ~a&Te. X p o ~B KonTaK-re c Memm HaxonuTcrr B wcnoii cpene (HCI). Ka~oiiMeTann 6 y n e nOnBCpraT6CX ~ K O ~ ~ O ~ F OnpefleJlLi~e ~H'? 3HaKW ~ O T e H ~ U i 3 J l OMCKMJIOB. lr Peme~ue.110 ~a6nnqes n a s e ~ n hi i n a p ~ ~ snemponHblx b~x noTeHquanoo HaxoAtiM, q T O 6onee aKTnBHMM MeTannOM I1BIUI€XCX X p M , H M ~ I O U H ~6onee 0I'p~qaTenb~blfi noTeHsnan. CnenoeaTenb~o,B 0 6 p a 3 0 ~ a ~ m e ~ranbeaHuqecKoM cn 3 n e ~ e ~ xr ep o ~6 y ~ e ~ quuaTenbHblM s n e ~ l p o ~aoMem ~ , - nonoxmknb~61~. ~JI~KIUOHH IlDOUeCC: ~I~ (-) Cr / HCl / CU(+) Cr - 2 e = ~ ? ' 2p+2e=~7 Cri ~~H+=c?+H* B MoneKynxpHoM sWe ro~oo6pa3yro~qa11 peawnn meeT cnenymquii nnfi: Cr + 2HC1= CrCI2 + Hz III'MMEP 2. B n u ~ ~ wnepeHarrpRmeHnx e peaKLluu BoccTaHoeneHnR oKncnnTeJln Ha C K O D O C T ~ K O D ~ O ~ U HK . ~ K m n e T aManbraMnposaHue anmMuHun Ha cKopocrb ero KOPp3HH B ~ T M O C ~ ) ~ YC~OBURX? PH~IX OKCUK~), npenoxpmamqeii ero ar nanb~eh~uero oKucneHnn. Ecnu ~ J ~ O M U Honyc-ru~b H ~ PaCTBOp COnU pT)TU, TO OH KaK 6onee W H B H ~ I ~M€TUUl ~ 6 y ~ BblTeCHIlTb e ~ ee H 3 pac~aopa: 2A1+ 3Hg(N03 = 2 /d(N03)2= 2AI(N03)3+ 3Hg B pcsynb~a~epeaKqnu Ha nosepxtioc-ru a r r r o ~ u ~ a nofipa3ye~cn LrsreliKa ~ e m n n u q e c ~ o' fm i u , mu, Towee, cnnas pryrw u m m ~ u ~- maManbraMa. Ilpn ~ T M O C ~ K P H ~ IYCJlOBUIlX X (Bnax~6lfi ~03nyX) Ha nOBepXHOCrki aMaJIbraMbl MMeeCCR TOHKWI IlJleHKd BJlaTW, B ~ 0 ~ p oPaCTBOpeH fi KHCJIOPOn. B O ~ ~ ~ ~ O R ~ B ~ U C ~ C R B MKI'ti LIPOl(eCC BOCCl'aHOtlJleHtiR KMCJ1OPOfi;I: (-) A1 / H 2 0 , 0 2 / Hg (4 ) C x e ~ ~a o p ~ o s n o ~npouecca: ~oro 4 A1 - 3e = A]'+ & + 2 H i 0 +4e=40R3 4AI + 302 + 6 H 2 0 = 4 ~ 1 "+ 120H4 ~ 1+ ~ 1' 2 0 H - = 4Al(OH), 1 pryrn. 06pa3ylouanc~ npn TOM p b I x n a R n n e H K a r u n p o l c c w a ~ J I I O M ~ H ~HRe npefioxpaHRa ero OT nanb~efirnero o m c n e H n R . n o s m ~ y CKOPOCT~ ~ 0 p p 3 n n a h 4 a I l b T a M U p O B a l i H O r O aIlK3MHHUR 3HaYUTeJIbHO 6 o n b w e , Y e M .lUCTOrO. 11PMMEP 3. B n w r l ~ n eC W n b l H a CKOpOCTb KODD03UH. B KaKOM U 3 B O W M X p a C T B 6 p O B 6 y n a 6onee K O ~ ~ O ~ H O HYHCOT O ~ ~ Y H Ba) : NaCI; 6) NaOH; B) N H 4 C I ? Pewe~we.a) B B O ~ H O Mpameope NaCI, B npucyrcrsun UOHOB Cl', O K C H ~ H ~n An e H K a H a nOBepXHOCTU M e T a n J I a PaCTBOpRtXCfl U HUKe5lb 6 y ~ KaO p p n U p O B a T b C K U C J I O ~ O ~ ~ H O ~ n e n 0 n R p H ~ e ~ 6) . B BOnHOM pameope NaOH n n e H K a r n n p o K c n n a H n K e m , 0 6 n a ~ m q a n OCHOBHMMH C B O ~ ~ C T B P M H , MaJlOpaCTBOpHMa, ll03TOMY K O P P 0 3 U O H H a R y C T o f i q H B 0 C ~ bHUKenR B 0 3 p a C T a a . B) B BOHHOM P a C T B O p e NH4CI K p o M e HOHOB X J l O p a H a CKOPOCT~ ~oppo3nn C y q e c r B e H H o we^ n p q e c c ru~ponn3a conn, B p e 3 y n b ~ a ~ e K O T o p O r O pH pacreopa w o a u - r c a H n m e 7 (mcnan cpena). C~uxettnepH pacmopa HwKenb YCkUIHBatX OKUCJltiTenbHylo C ~ O C O ~ H O C T ~K U C n O p O n a NaCI. IIPMMEP 4. KaTon~axs a ~ u u ~Ma ~ ( C ~ ~ B H U CTaH&3pTHble HeCTOeK, Y e M B P a C T B O p e nJIaCTHHb1 HaXOnRTCH B BOAHOM T ~ OOTB K O ~ I M ~ W U . ~ H H K O B ~ H X PacTBOpe NaCl xene3~an ( a ~ Z U l 0 r M O P C K O ~ ~ B O A ~ I ) ti flOACOeAMHeHbl K B H e l l l H e M y UCTOYHUKY n O C T O R H H O r 0 T o K a : l(WHK0BM - K (-1, a X e n e 3 H a R K (+). K a ~ a nW 3 M a C I . H H 3 a U I U q e H a O T K O P P O ~ H U ? 3 a n H l U ~ y~pea B H e H U R K O p p O 3 U O H H O r O npouecca. C k e ~ snemonn3a: a Fe - 2e = ~ e ~ + 2H20 + 2e = Hz + 20H' Kt: Fe + 2 H 2 0 = ~ e + ~20H' + + Hz ~ e ~ 20H+ + = Fe(OH)2 An: HaX0.4II~HXCSBO BnaXHOM rPYHTe. (-) Zn / H20,02 / F4+) C x e ~ KOI)~O)OJHOHHOI-O a nDouecca: Zn - 2e = zn2' 2 O2 + 2H20 +4e = 4 0 K 1 2Zn + 0 2 + 2H20 --- 2znzt + 40HIIPMMUP 6. n p ~ ~ e t l e ~3a~OtiO~ kie Oapaaefl K KOppO3MOHHblM npoqeccahi. CKOPOCT~ K O P ~ O ~ McTann H B ~ncnoiicpene 0,2 r/h?*r. 0 6 u m nnouaAb noBepxHocm c~anbtioh KOlicrpyKUHtl 100 M ~Ka~oii . CKJlbl TOK I l Y X H O nPOnYCTWTb YePC3 Cl-dJIbllyl0 KOHCQlYKL(HE0, ' I T O ~ ~I Il O ~ H O C T b f OIIOnaBHTb K O P P O ~ W ? Pelue~ne.06ruee yMeHbureHue Maccbl cranw 3a 1 vae cocramnm: ' n o J ~ K O H YOapaue~cnna ToKa, ~ e o 6 x o n n ~Ann m nonasnetinn ~opposnn, I = m .FIT 03 nnn I = 20.96500/3600.28 = 19A. BOnPOCbl M 3A.QA411 4. K a ~ o hu3 ~ c r a n n o c~ ,nonnposa~~oi3 nnn ~cpoxoaa.roRnoncpxtiocrbto, Gyuc~ KOppoAHpOBaTb 6b1c~pec n noqe~y? 5. K ~ Kannflm-r Heo,qHopoAHocrn c~pyk-rypb~n cowam MeTanna ria cr-o 10. BOA^ H e A C M C T B ~ C TH a U I l o M k i H l l f i U a X C I l p H 1 1 0 t l b l ~ e H ~ 0 Tf ie M l l C p a 7 y J E . f l 0 q e M y npn n o l l m a H n n R BODY NaCl a n l o ~ n ~ u Hf ai q n l i a e T ~ o p p o n n p o s z r b ?B pacreope K a K n x coneFi NaCl n s l n N ~ ~ 0 c1~ 1o p o c ~~ ob p p o 3 n nAl s b ~ l u e ? I I . 1 1 0 ' 4 e M y X e J l C J O , M e l i e C ~ K T M B H ~MI e~T a~R n , K O P P O A t i P Y e T B ~ T M O C L $ ~ ~ H M X YCnOBURX 6 b 1 c ~ p e e~ J I I O M M H W I ?C ~ ~ B HK OUp pT0 3 W ~OHHyIO NaCI. Y C T O ~ ~ ~ H B 3TUX C K TM ~ elXJUIOB B ~ H C T OB ~ o n~e U B BOAHOM p a C T B O p e I i p o l l e c c ,ul.rlnrnpol!alinH ( H ~ C ~ I I I ~ ~I I IO~B H ~ PCX H O C T HM e r m n a 15. K ~ K H MMClOfiaMCI H 16. K a T o n ~ b l h Mnll l~ 20. K a ~ n eH3 anm~nrine~)? MOXHO C 0 3 A a T b H a IIOBCPXHOCTU M e T a J l n a 3 u n T H b l e C ~ O H ? aHOAHblMH IlLUIRlOTCH AJlR mene3a IIOKpbSrHH U3 Zn,Ni,Sn,Cr? M e U H RBJIXtOTCII ~an6oilce KOppO3MOHHO (20% - 80% CU, o c r a r l b l i o e Zn); 6 p o ~ 3 a :( 9 0 % C ~+ 10%Sn); 20% Ni) I I p H B C ~ C H H b I X CWqaBOB Y C T O ~ ~ L ( H B ~ I MJ H l X?r y H b : ~ e n b x t i o p (80% : 24. LyAeT Cu -i n n xes~esoK O P ~ W H O H H O y c ~ o i i r u ~B oB O A H ~ I Xpansopax NaCl, Cu(N03)2, N i C 1 2 ? 3 a l l H l I l k i ~ CCXeMbl K O p p o 3 H O I i H b I X I I p o ~ C C C O B . 25. K a ~ o i M3 i M m J I O B , Ije U n n Mg, 6 y ~ e T6onee KOppo3).10HHO CTOeK npn pH>7? 26. Kopponnpyer JlH M e n b a B O A H ~ I X pacrnopax HCI, N I - 1 4 O H B npncyTcrsuu 28. I I o ~ l c ~u yO ~ ~ C K ~ ~ C J ~ n ~o i t~e O xeneso X ~ ~nH p a KOr n a l c c K n l i e K o p p o n n p y e r , a . r ~ o c + c p ~ i ~ , r xy w l o s n s r x cttopwrb ~0ppo3nn a u X ~ J I C ~~H ~~ ' I W . I . ~ J I I , H ~ '~? ~ I I ) ~ I ~ I H . I . ~ B 0 3 M O X H b l e CXCM bl KOPP03CIOH HMX IIPOUCCCOB. 29. K ~ UIIWHK)T K H a CKOpOCTb KOppO3WCI UUHKa I ~ p t i M C C l i C'U, I'b, Fe? 30. K a ~ n e I l p O ~ e C C b l npO'reKaIOT i l p t i K O p p 0 3 H H OQHHKOHaHHOI.0 X e J l e 3 a C HaPYrUeH HblM IlOKPblTWeM B BOAHOM P a C T B O p e NaCl cl B a ~ ~ ~ ~ ~ e~ C p ~ lO iB Hb Hl X ~? C O C E ~ B ~CXehibl T C KOPP03UOHHblX TaJlbBaHW'IeCKCIX 3JleMeH'COB. K a ~ y t oP O J l b H r p a e T n p n c y T c T e n e B B o n e xnopwa H ~ T ~ H X ? 31. O U W H K O B ~ H H ~LIIM O M e A H e H a R X e n e 3 H b l e ILJlalXHHbl C HapYUreHHblMH flOKPblTWIMW HaXOflTCR BO B J l m H O M B03AYXe. Ha K ~ K O H3 ~N l a l X k i H IIOHBrlTCFi pxal3'4Lil4a? C ' o c T a B b ~ e CXGMbl KOPP03WOHHblX raRbMHUYeCKUX 3neMeHTOB 3allHUIWTe W YpaBHeHHR n p O T e K a l O l 4 W X p~aKu&ifi. 32. ~ J I I O M ~ H HllJlaCTkiHa C ~ B K O H T C~ ~ ~m e 3 ~ 0 HaXOlVlTCH i i B M O P C K O ~ BOAe. C ~ a ~ o, qiein o n n p u s a q n e i i n p o T e K a e T KOPPO~WH?3 a n u ~ 1 ny~pea e ~ e ~ pea~qnii. in~ 33. K ~ IKl p O T e K a t T K O P P 0 3 W I I t j ' l K e ~ ~ MeAW k C H a p y r U e H H b l M IlOKPbITHeM B K H C ~ O ~ CpeAe W B ~ T M O C $ ~ ~ H ~ C I X~ O B H X XK? a ~ o 5M ~ T a l T J lnOnBepCaeTCX KOPPO~HCI? C ' O C T ~ B ~ T ~ CXeMbl KOPP03WOHHblX ~aJIbBiLHWYeCKUX3nGMCHTOB W 3aIlHUH'Ce peaKUHki 34. O ~ ~ H C HnH O qT eM ~y, U H K O B O e a H k i K e J l e B W AOJIXCHO 6 ~ IIOpWCTblM, 3 a U n T H O e nOKpblTlle CMOUIH~IM? ~ b H a CTaJlIz M O X e T 6b1Tb C O C I ~ ~CXeMbl B ~ T ~KOPPO3WOHHbIX n p O q e C C O B J&IUl~ T M O U $ ~ P H M X ~ c J I o B u ~ ~ . 35. K ~ KD p O T e K a e T KOPP0311R XPOMKPOBaHHOTO CTaJlbHOCO kl3AeJlUH C H a p y l l l e H H b I M wcnofi n B ~ e f i ~ p m ~cpenax? o i i 3 a n n u n ~ Ke O P P O ~ U O H H ~nI p~o q e c c b r . 36. Ka~ofiH 3 M e T a n n O B n O A B e p r a e T C H KOPP03HH, eCJLU H H K W P O B a H H a R CTaJlbHaR AeTLLJlb C HaPYUre+blM n O K p b I T U e M HaXOnHTCH B K U C J ~ O cpene? ~ C o c T a H b ~ eCXeMy n o q m m e M B KOPP03HOHHOrO TaJIbBaHHlleCKOrO 3 n e M e H T a H 3 ~ W l l l H R peaKULiH. 37. C p e n e . K a ~ o i iMeTaJln 3 a q n u e ~ ~ eo ~~ m n e ? n3 pacrsopos: c y n b 4 m a nnn xrropuna M e a n , ~ H H K6onee s H e p r n r H o b ? Y ~ U T ~ I S 'IT0 ~ R , B p e 3 y n b E 3 T e r U A p O ~ U 3 a cone5 C p e n a m n X e T C X H W K e n b B KOHTaK-Ce C MeAblO HaXOAUTCH B KUcJIofi n o n B e p r a e T c 2 KOPPO~UH? K a ~ a n peaqnx n p o T e K a e T H a 38. B KaKoM BblTeCHXeT ~ e n . cna6o~ncnofi,C O c T a B b T e CXeMbl 39. O ~ ~ H C Hn OHY eTM~y B, M KOPp3HOHHblX lIpo4eCCOB. e m KOHTaK-ra C T a n H C &rlH)MHHHehl B 0 3 H H K a e T R3BeHHaR KOpP03HX FlJltoMHHHH. 3 a n H U l n T e KOPP03ROHHble n p o U e C C b 1 AJlX E f T h l ~ ~ ~ e ycno~tifi. p ~ b l ~ 40. ~ e n e 3 0 ,IIOKpblTOe CBHHQOM H a X O m T C H BO M a X H O M r p y H T e . K ~ K6 y n e ~ npki H a p y U l e H K U 4CJlOCTHOCTH ~ o K P ~ I T H H K~TOAOM ? ctnu aHOnOM 6yne~ ~ c e ~ l eB s o0 6 p a 3 0 ~ a s ~ l e i iranbmonape? c~ 41. M e A b H e BblTeCHHeT BOAOFXlA W3 p a C r B O p O B M C n O T . O A H ~ Ke COn H K M ~ A H O ~ n n a c m e , onyue~aofiB K Z I C ~ O T ~n,p u K o c H y T b c x ~ H H K O B O R n a n o q ~ o i i , TO H a M e m Ha'iUHaeTCH 6j'p~WB b I A e ~ e H H eBO&OpOJla. ~ O Y ~ M Y ? 42. B b r n e n e ~ n eB o n o p o n a H a n n a c T n H e n3 s n n o r o x e n c r l a , o n y q e ~ ~ o Bf ip a c T B o p I I p O T e K a T b KOPPO~AX C O J I X H O ~KHCJlOTbl, ~ I l p O T e K a e T AOcTaTO'IHO M e m e H H O . C ~ o p o c r bB b l n e n e H U H B O n O p O A a 3HaLLUTeJlbHO BO3paCTaeT, e C n U Xene30 6 y n e ~HaXOAHTbCR H ~ M ~ H H ~ OKa~oii C ~ ? H 3 MeTFlJlJIOB I2 U KOHTaKTC C UUHKOM. 6yna K O ~ ~ O A H ~ O B ~ T ~ ? q10 ~, 43. Y r w ~ ~ e BC m JIWIH ' HY 06bnc~n~e n 0, l l e M y C MeAblO IlCpeHaIIpRXCHHR peaKuww eocmtloanetiwn Bonopona, e m KOPP03WI0, a KOHTaKT aMaJlbmMHpOBaHHe UWHKa pC3KO CHMXatT - y ~ l H ' i H B a ~3?a n ~ l l I W T eKOPP03HOHHble npOUeCCbl. 44. I I o ' i e ~ yKOHTaKT C H H K a e M YCHnHBaeT KOPP03HlO UHHKa B KHcJIoE cpene? Ha KaKOM MeTaRne W nX l BblneJleHHe B O ~ ~ O ~ O LB( ~KOHTaKFe ? C KaKHM MeTannOM, M K M e M UW I nnam~oii,UHHK K o p p o n n p y e T 6 b 1 c r p e e ? 45. Kax W W R a KOHTaKT C HWKeJIeM, KOPPOJHW o n o B a B Kwcnblx 46. H H K ~ JOIW~H b CBWHUOM W MenbH) @a3fleJlb~0) cpenax? 3anuun~ec x e M u H a CKOPOCTb K O ~ ~ O ~ W O Hnpoueccos. H ~ X M e m e H H O Bblnt3MeT BOnOpOn H3 KHCJIOT. n 0 q e h 4 y BblfleJIeHuR BOnOpoAa H a HHKeJle pe3KO BO3paCraeT, eCnH OH HaXO-R CKOpOCTb B KOHTaUTK2 C r n o~ ~ w c n ~ a c mn? o r e ~ yBblneneHne sonopona wne~ w~ene? 47.B KOHTaKTe C KaKWM W3 MeTannOB, Pb W n W Fe, UWHK %nee KOPP03WOHHO H ~ C T Q e KB K a ~ o i ~i UHHKOM? e ~ a nnpn n npenMylqemBeHHo Ha ~ ~ o p c ~ oBone? i i OTXT n a i i ~ eIla oc~iooa~iww nalilrwx: I ~ ~ ) ~ ? = - T ) ~ $ ' 48. n o r e ~ y npn. c c n e ~ w e ~ o i KOPPO3HH 4 CKOPOCT~ p a 3 p y u e H w g M e T a n n a co BpeMeHeM y e e n w r n s a e ~ c ~ ? 49. Mar~wesmw m e n e 3 ~ a r r n n a m w H b l , H a x o m q w e c R B BonHoM pacrsope NaCI, nOflCWnWHeHbl K WCrO'lHHKY HOCTORHHOI.0 TOKX Mg K (-), a Fe K (+). K a K a H3 WlaCTWH 3 a u n l u e H a OT K O P P O ~ W C ~? o c r a s b ~ ec x e M y KO~POJHOHHUX npoueccos. 50.C T ~ J I ~ H KOHCrPYKUWR ~R HBXOAWTCR B npW ee KOPPO~W~'? K ~ K W3MeHWTCH M O P C K O ~Bone. Kame 11pO~eCCblnpOTCKalOT K O P P O ~ W O H H ~ nPOI1eCC, I~~ eCnH K K O H C r P Y W H H n p n c o c n w l i w r b UWHKOB~Iii r ~ p o ~ e m o p ? 51 . MCI'OJ. UJIR 3aUWTbl C T a J l b ~ o f i KOHCrPyKUW W OT KOPPO3WH HCnOJlb30BXilH I C a T O a ~ b l i i 'ICM OH 3 a K n ~ > ' l a e ~ ~ K Ra ? ~we IlpOUeCCbl 1lpM 3TOM ~ ~ K . K ~ K ) T ? 52.K a ~ ~ a t i b lMeTOfl3alllWTbl ii IlaPOBblX KOTnOB OT KOPP03WH 3aKJUOYaeTCR B TOM, 'IT0 onHwM n 3 3 ~ 1 c ~ r p o naknReTcR o~ caM or en, a npyroii KoTna. I l o n a e a c ~ b ~repes ii ~ a ~ y ct woc r e ~ y c n a 6 b l i i TOK 3 n e l r r p o n n o ~ e r u a a c neHy.rpw n o n a m a K O ~ ~ O ~ H HK )a. K ~ i ni 3 ~ n e ~ r p o n ow nn o r e M y R m a e r c m ~ a m ~ o ~ ? 53.X e n e s ~ mKOHC~P)~KUWR, H ~ X O A R W ~ C I I B ~ o p c ~ o one, i i ~ e p ~ I0 e rK r M e T a n n a B r0.4. K a ~ o i CWJlbl i TOK tlW0 nOAaTb H a KOHCTPYKUWK) npki K ~ T O ~ H3O W~ WTe, r m 6 b 1 llOnHOCTbK3 IlOnaBWTb KOPPO~WH)? 54. K a n ~ w i Bi KOHTaKTe C cepe6po~HaXOAWlCR B K H C ~ OCpene. ~ ~ K a ~ y mC W y TOKa ecnn 3 a 2 raca ee pa60~bls h l n e n n n o c b 0,2 n naeT 0 6 p a 3 y m u a ~ c ~ ravbealionapa, Bo~o~o&~ CKOJI~KO ? lQaMM0B MCTaRlla n p H 3ToM O K H C ~ H ~ O C ~ ? 55. Xenesl~arr n n a m w H a Ha ~ o 3 ~ y xnpn e ~ b r c o ~ o Ti ei M n e p a T y p e o t c u c n R a c a c o 6 p a 3 o ~ a ~ nHea ~ee n o s e p x H o c r w o K c w n a F e 2 0 3 . 3a 3 q a c a M a c c a n n a m n H N n n o u a n b l o Iu2y e e n w r w n a c b H a 10r. P ~ C C ' I H T C~ p~e. n~H m l o c ~ o p o m bK O ~ ~ O S W H . 56. C i a n b ~ o i i6 a ~ m os ~a ~ i o n ~Kcw~c n o p o n o M c n p n M e c b m naporr BOA~I. q c p e 3 I l e K O T o p W BpeMR KOJIH.leCTB0 KtfCJlOpOna B HeM YMeHbUlHJlOCb H a 0,1 n. P ~ c c ~ H T ~ T CKOJlbKO rpaMMOB MeTanJla I l p H 3TOM llp0pC!i3I.WpoB~0? 3allHcaTb CXeMy KOpp03WOHHOrO npouecca. 13 (H.Y.). C K Q ~ ~ rPaMMOB KO iLlllOMHHWR npH J r o M OKHU~HS~OC~'? 58. rlpH CTOIlHKe CyAHa y npHriIna plur W u T b l er0 KOpllyCa OT KOPP03HW lPWMCHRtOT K a T O W p WHT)'. f i o ~ a j &n o ~ m o racrn A CyflHa 1000 M'. CKOPOCT~ KOpp03WH 6e3 r/M2 B CVKU. K a ~ o i CUSlbl TOK H W O nOAaTb Ha npHMeHeHHR K ~ T O 3aWThI ~ O ~ KOpnyC CyAHa, ~TO6blnOnHOCl'bH3 nOAaBHTb KOPPO~WK)? 59. C p o ~cnyx6b1 cranb~bix n p e ~ r u ~ ~~bp~yx6o6qeii moqanbm 10' ,'M KOppofltlp~loqwx6 ~OJIOTHOM rpyHTe CO CKOPOCTblo 10 r/M2 6 rOn, COClXl3SlReT 20 AeT. C ~ o n b ~UWHKa o (no M ~ C C~ ~e )o 6 x o ~ B3RTb n ~ o N R ~ ~ ~ T ~ K T O ~3aqnTM H O A v y 6 , rro6bl cpo~ HX cnym6b1 yaennrnrb 6 AM pa3a? OIlbI'I' 1. BJIHHH~C WBKUHN CPeAbl( pf( ) Ha CKOPOCTb KOpI)03NH MCTaJUIOB &A cpaeHeHnn annnHnrc xapampa c p e ~Ha~ c ~ o p o c ~~0ppo3nn b McrmnoB; ~ a n e i i ~B eH W X no 3 MJI: 1) 20% pamsopa NaOH; 2) ~ ~ ~ ~ ~ B J I ~ H I: H IOpacnropa I ~ O HCI; 3) ~ H C T OROJlbl ~ $ I Kall~llo( P ~ H o ~ @ E U ~ ~ BWKHW~Y. W ti3 11po6npo~ OnyCTtiTe no K Y C O V K ~ nepsoro Merarlna w ~a6nloflaii~e KaK npoTeKae-r Kopponnn (ecrh nnn Her OnblT CO BTOPbIM MeTaSlSlOM. nOCTp0fiTe rpa($nK 3aBHCHh30ClC4 CKOpoCTii ( ~ I ' H O C C ~ T ~ J ~KO ~PHPO O3W CW ~ )UT PaCTBOpa. OIIbI'I' 2. A ~ o f l ~ b VCK0l)Wl'eRM le ~onpo3nn a) B n n ~ ~ nWlOpHfl-MOHO6 e Ha CKOpOCTb KODlIO3nti MeTa1l~lOB. 13 Nee llp06np~n HaSleK~eno 3 MSI 10% PaCTBOpa cynb($XTa Meflti CUSOj. B IlepByK) llpo6~pKyno6asbi.e HeCKOnbKO Kanenb HaCbllUeliHOrO pacTBOpa NaCI ( H A t i KpMClZlJlnKoH NaCI). 3LTre~6 Kawpjw n p o 6 n p ~ yn o n o x n ~ eno KYCO~!KY Al WJIW ZII. O~ipe,ue~~wle, H K ~ K O Mclyqae shlieclicHne Menw n3 ee pacreopa rlponcxonnT %nee nH.rcHcnnrlo. 0 6 b ~ c t l n ~~ cO J I WOHOB x~lopa. 6) BnnRHne npouecca K O M I ~ J ~ ~ K C O O ~ ~ ~ ~Ha O Bcwopoc'rb ~HHX ~opposnn.B ripo6np~y ~arrcii.re 6 Mn 25% pacreopa aMMnaKa n rioJioxnre KycoreK hqc,un. MHT~HCWLI~IO 11epeuel~1aiii.e.tla6nmaaR.r~ nHreHcnsHoe oKpawnaaHne pacTBopa B c n ~ w i iqncr. 331.0 O~LHCHRCY~CHnepexonoM Menti 6 PaCTBOP 6 BWAe KOMnneKCHblS HOHOB [ c u ( N H ~ ) ~ ] ~. ' 3a11nwn~eypasHeHnn IlpoTeKamqnx npoqeccoe. C K ~ K O A ~crlo~1npnsauneiinjier Kopposnn Menn B TroM c:~yrae? I l o r e ~ ynpoqecc ~ o ~ 1 ~ n e ~ c o o 6 p a 3 o yecslnrnoaer ua~nn ~ OllLl'l' 3. Il~~nwtlwe Ilepcnanpaxellww praKqMw ~ ~ o ~ c ~ . ; ~ t t t r r , - rIcogltrl)o,l;i c t ~ ~ ~ t r II;I CKO~0C.l.bK01)[)03HH. B03bMn~ rpally~lblZn WlH A1 (110 3illiljlilllCIIL) I I ~ X l l O l l i l l l ~ l C J I H ) O A HH~3 HWX nOMecTHTe Ha 2-3 MHHYrU B CTaKaH'IHK C 1M ~dCrBOi)OMCy~lb4MrdMMeln (CuS04). B H H ~ rpaHyny T~ H ocropomo r l p o ~ o i i x~ ~ c r ~ n n n p o ~ a BOAOR. ~ i ~ oBi i,we , npo6np~w HarlefiTe 1M p a m q C O J ~ R H OKHCJl07bl ~~ (110 2-3 ~ n ) H OnyCTHTe B HHX UwiKoBbre r p a y n u . H a 6 n l o ~ a i i ~n ew e n e ~ n eBoAopoAa. B m ~ o i ni p o 6 ~ p ~ BuneneNe e sonopona npoTeKaeT &nee HHT~HCHBHO? O~T,RCHHT~ ~ a 6 m n a e ~ oCocm~bre e. cxeklbl KOPPO3WOHHbIX rUlbBaHW'leCKHX 3JleMeHTOB npH KOPP03M WmOIY) H OMeAHeWIY) U W H( ~ ~ ~IOMHHWR). OnblT 4. A H @ ~ H nH ~ rmTonHble nowpbtrna Ha merannax. B J W ~ npo6~p~n ~Cmeii~e no 5 Mn 1M pacrsopa c o m ~ o i iKHCSIOTH, ~ 0 6 a ~ bno~ 2e kcaru~~ paCTBOpa Kpac~oiiK ~ O B X H Oconw ~ ~ ( K3[Fe(CN)G]), ~ o ~ o p RBJIR~TCR an ~ ~ ~ K T H B Ha O MH O H ~ I~e". B [repeym npo6up~yonycTwTe nonocKy ounHKoemHoro menesa, a so tnopyto - nynceHoro xe.llesa. I lpeneapn.renb~o nosepyoc-rb nnacTntioK s a q w c ~ n ~~e a m a q ~ o 6y~aroii. ii 17oxane~ne cnHero otcpalunsatinn pacmopa csnne.rerrbmya o nonanetinn w o ~ o s x e ~ ~ e n, s a sriarn~,o npouecce e m ~opposnn.B KaKoM cnyqae xeneso ~opponnpya*? K K ~ W M IIOKPLITWRM OTHOCRTCX mn menesa U U H K O B O ~w onoasHHoe ~ O K ~ ~ I T H ICI 'O ? CT~B~T CXCMbI KOPPO3WOHHblX I'aAbBiFHWVeCKHX 3lleMeHMB W 3anHIlIHX YpaBHeHHX ~rpcrre~amqnx r~poueccos. OIILI'r 5. ~ J I ~ K ~ ' P ~ X ~ I M MeTOAbI H ~ ~ C K3all[MTbI H ~ M ~ T W l J O BOT KODPO3 ' HW a) n u o r e m o ~ ~ a saunm. w B CTaKaH c 20% pacTBopoM NaCl no6asb-re 2 Kannn @et~o.il+ra.len~a, K U I D P ~ TB~ ~qenoq~oii cpeAe AaeT Ma1ntiosoe oKpalunsaHne, n OnyCTHTe COCAkiHeHHble npOB0~HHKOMMacrnHl4 H 3 E'e U Zn. OKOSIOK ~ K OMaCTHHbl ~ tlOXBnReTCH MUtHHOBOe ~Kpa~tiIjiFH~~we? C O C T ~ BCXeMy ~ X KOppo3HOHHOrO np0UeCCa H ' . sarrwu~n.rerlpo-re~atounepealcqnw. K a ~ a nn3 ~ J I ~ C Tsaulwqe~a ~ H ur ~opposnn? 6) Ka'ron~m3 a q n ~ a B . CTaKaH C 20% PacTBOpOM NaCl no6asb~e.2Kannw K ~ ~ c H o K ~ O B R H OCO-VW ~ ~ ( p e a ~ Ha ~ nHOHH ~ ~ e ~ n+onycrnx ) nee merres~brennacrnnbl. O r ~ e ~ b ~ 1IOHB:leliHe CH IiCI'O OKpalllW BmM, YKa3blBaK)~erOHa IlpOreKaHHe KOppO3HOHHOm npoqecca. I loficoefinlin~ennacTnHE.1 K P ~ ~ H ~nonmcaM I M nmrHnKa CIOCTOHHHO~OToKa. OKOSIO K ~ K O Rlulac.r.wtib1 rroxsnsmcx cnHee oiqalunsa~ue?K a ~ mns ru1ac.rwH s a u n u e s a O'l' K0pp0'3Hki1?3allkilll~K!YpaBHeHHR KOppo3nOHHblX npOqeCCOB.