169 Для кристаллов типа NaCl замещаемые атомы составляют
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169 NaCl (қ) Nfreq/Natoms – , – ғ , , , θғ ғ ғ ( ғ , ғ 1. , ) ln ғ ғ, ғ ғ, – ғ ғ ғ ғ// ғ ғ ғ « – ». - ғҮ4. -2007. – ғ 157-160. 2. Urey H.C., Bradley C.A. The vibrations of pentatomic tetrahedral molecules. – Phys. Rev., 1931, v. 38, p. 1969 – 1978. 3. ғ ғ ғ– ғ – 2009. – ғ - ғ қγγғ 4. Bigeleisen J.//Proc.Nat.Acad.Sci.USA.Phys.Sci. -1981.- VғҮү, Ұғ - P.5271. 5. ғ ғ, ғ ғ – ғғ– 1999. - ғҮγ, ηғ - ғүҮη – 879. 6. Barron T.H.K., Berg W.T., Morrison J.A.// Proc. Royal. Soc. - 1957. - V.250, 1260. P.70. 7. Myrzaliyeva S.K., Dauletbai A.D. To the problem of search of perspective chemical interchange systems for division of isotopes of biogenic elements // 14th Conference on Environment and Mineral Processing, OSTRAVA. - Part 1. – 2010. – P. 251-255. ғ ғ , ғ ғ , ғ ғ , ғ ғ , . -mail: vkorobochkin@tpu.ru , , ғ ғ - ДҚ, қЖғ , ДҚЖ, ғ pH, , ғ Дγ–5]. ДθЖ, , , , , , , ғ Mn(OH)m ғ , ғ ғ ғ , 170 ғ 100C. Қ0η–ҚҚ0º ғ NaCl, % 3 3 5 15 15 20 25 25 қ0–Ү0 ДҮЖғ ) ( ғ SDT γ% NaCl ғ Қ), γ%- , ДүЖғ SnO2 SnO Sn2O3 ғ 2 ), SnO , SnO2 ( қη% ғ , Қ0 / , Sn3O4 , ғ SnO2 қ)ғ , SnO Qθ00 - , U=қ0 SnO ) (I=қ0 (қ) SnO2 ( SnO 2 / ) - , / 2,0 3,0 3,0 1,0 2,0 3,0 2,0 2,5 SnO SnO2 ( , ғ, ғ SnO2 ( Cu -γ , ғ SnO2 1 2 3 4 5 6 7 8 , ғ 1 2 20 30 40 50 60 70 2, Қ қ ғ Қғ , , SnO , ғ SnO2 Sn2O3 NaCl c Sn3O4. , γ% ғ 171 SnO SnO SnO2 SnO2 SnO2 SnO SnO2 SnO 8 7 20 30 40 50 60 2 Ү ү ғ қғ ғ ( ғ 3, 4) , - Қ-4 ( ғ 3, 4) ғ - , Қ, қ00–250 70 ηη0–750 ғ (IV)ғ - , ғ Қ–4 , SnO2 , SnO, - Қү0–200, 300–310, 380–400 ғ (Ққ–14% ( ғ) (II), (IV)ғ Sn(OH)2. ғ 3, 4) 4θ0–470 , , SnO2 nH2O, m, % 101 қ–4 n=1,6–1,8. Q, / 0,5 99 0,3 2 1 0,1 97 1 95 2 93 0 300 600 , ғ γғ ( ғ)ғ , ( ғ 4), SnO2ғ -0,1 -0,3 900 Қ қ (Ққ0–480 ) (IV) 172 4ү0–900 ғ SnO2ғ SnO2 ғ 4η0 m, % 101 , , , Q, / 0,30 3 99 0,15 4 97 0,00 3 -0,15 95 4 93 0 , γ Ү ү, ғ η)ғ ( , ғ , -0,30 900 600 [9]. ғ 4ғ - 300 ғ Үқ0 ғ ғ m, % 101 қη% NaCl γҮ0–430 4,0 , θ,η%ғ , 4 ғ, SnO , - Q, / 1 1,0 100 8 0.8 0,8 99 7 0.6 0,6 0.4 0,4 98 0.2 0,2 97 7 96 0 0,0 8 -0.2 -0,2 95 -0.4 -0,40 900 94 0 300 600 , ғ ηғ - , Ү ( ), ДҚ0, ҚҚЖғ ғ η , SnO, ү , θ – , SnO2, 173 ( зқ γү0–720 η θ 620–640 ғ , ) қη% NaCl ( ғ SnO ), , SnO2ғ , NaCl Sn(OH)2ғ , , , , – 4қ0 ғ Қη% ғ ғ , , ηҚ0–ηқ0 γү0 , SnO, , 6 ,% 5 4 3 1 2 3 4 2 1 0 0 10 20 30 ғ 6. 40 50 60 , Қ-4 . 6 ,% 5 4 3 5 6 7 8 2 1 0 0 ғ Үғ 10 20 30 40 60 , η-ү, Ұ00 , ғ 50 - - , ғ , 174 ғθ Үғ ғθ Ү , , ғ θ,Қ%, , қη% NaCl , ғ , , NaCl ғ , , ұ , γ,қ– γ% ғ, ғ, – 1,9–4,3%. Cl– , ДθЖ, ғ , ғ , ғ қη% γ% SnO2ғ ғ ғ, SnO. 1. Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions. – L.: Pergamon Press, 1966. Pt. 2. – 386 p. 2. ғ ғ ғ – ғұ , ҚҰҮ4ғ – 71 ғ 3. ғ ғ, ғ ғ, ғ ғ, ғ ғ 4. 5. ғ // ғ – 1985. – ғ 21. – 10. – ғ 1287–1292. ғ – ғұ , ҚҰθҮғ – 232 ғ ғ ғ ғ– ұ , ҚҰүηғ – 280 ғ 6. ғ // ғ – 2000. – ғ 36. – 10. – ғ – 1191–1196. 7. ASTM Diffraction date cards and alphabetical and grouped numerical index of X–ray diffraction date. Philadelphia, ASTM, 1967. 8. ғ ғ, ғ ғ , // ғ – 2004. – ғ 307. – 4. – ғ 101–104. 9. ғ ғ, ғ ғ, ғ ғ, ғ ғ, ғ ғ, ғ ғ // ғ – 1994. – ғ 30. – 1. – ғ 83–86. 10. ғ ғ, ғ ғ, ғ ғ, ғ ғ // ғ – 2002. – ғ 38. – 9. – ғ 1087–1090. 11. ғ ғ, ғ ғ , // ғ – 2003. – ғ 306. – 3. – ғ 89–94.
