4»E.QEP nb OE A EHTCTBO no 06PA30B M\t1HII1CTEPCT8 06PA30BAHV1~ t'1 HAYK POCCLltV1CKOltt <t>EJJ;EP llltWl H) . 3 .I TV1~ ~a 5EP V1nm.1111 11 ATPV1 ~ 19 ( V1~ Cu 9 !E,Qb Y 5V1 ,Q V1 ~ 7 Ag EPE6 PO 55 ~s E3V1111 - 12 Mg MArHV1111 20 Ca KAnbWV1 111 30 Zn WV1HK 37 ~b 4 Be 38 Sr CTPOHWV1111 48 Cd KA,QMV1111 Ba 56 5APV1111 J ono ·r T 11 IIltO a ie, 06­ Y JJ;K 54 1.123 6p a6 a ­ 101' r.M. nOJ1TOpaQKUii, 113 : n e KTp :0 (2H , :H). coen a­ A.H. EBAOKIIMOB, B.C. rOmIKOBa, A.B. KYP3UH A~ K orO~H 3 QHAH MJJ;A KAAM R (Caaxr-Ilerepfiyprcxnii roc ynap crseaasrii TCXH o n o r w l e CKHH yHu BepCHT eT e-mail: zakora@ mail.ru p a CT HTeJIbHblX nOJIUM Cp OB) 'BCTCT ­ Onpeoeneua pacmeopussocms uuanucmozo KMUll 6 sternauone U enuuepuue c yuemou otip asoeanuu coomeem cm ey toui ux aJ1KOlOJlllm06 KMUll i n ozi­ ro Ha­ Kmo-rem. re U HaH u ,n:bI llffiCKOH ne SSR. BbUI.9. CJlOB a : IJ.UaHU,n: KaJIH5I , M eTaHOn, r nUIJ.epUH, aJIKOrOJI5ITbl , p aCTBop HM OCTb menoxastx IJ,U a H H,n:a KaJIU5I U COOTB eTCTBYIO ru.er o paCTBOpUTeJ151 rOT OBUJIU fOTClI ,il,a HH ble 0 paCTBopUMOCTU IJ.UaHu,n:OB M eTaJI JIOB coc yn [1-6J. n, coen. CBe,n:eH H5I 0 p aCTBOp UMO CTH Qu a H H.D:a KaJI U5I B OhIX KHCJIOT H zrpyr a x np oaasoznrsrx l..II,CJIOqHbI X MC­ oprorpocrparu , cyns­ TaJIJIOB, TaKUX KaK: Kap60HaTbI, ~ HJJ:bI, Qu aHU,lI,bI, rnnpoxcansr, aIJ.eTUJlCHH.D:bI, aMU­ asansr U MeTaJIJIOOpraHUqC­ MO)KHO pacc ssarpnsars KaK cnocof il.hI, rH,n:p u ,n:bI , HUTpU,n:bI , s. 2000. ), T. 36 . I. V. 36. Chern. CKHe coc,n:U HeH U5I nOJIj"leHH5I COOTBeTCTBYIOI.I.UiX aJIKoron5lTOB: M nX + ROH = R OM + M n.IHX, (1) rae M - l..II,eJIOqHOH M eTaJI JI; X - C 0 3, S, C N , OH, C=CH, NH2 , H , N 3, N, P 0 4 , R; R - aJIKMJI; n = 1-3. Hasm onpenenena paCTBopuMOCTb naaanna KaJIl1l1 B MCTaHonc U rJIHIJ.epuHC C ytlCTOM 06pa30Ba­ HHlI COOTBeTCTB ylOllJ,UX aJIKOrOJI5ITOB. ;[3B. BY­ 3-115 ; II Izv. 13. N 3. 3eCTIlliK Vestnik ~-15 (in ransasre zramrsre npa s enea u 3 KcnepHMCH ­ B Ta6JIuIJ.e. Tatinuua PacTBopu MOCT b unauacr oro KaJllf H B MCTaIlOJ1C II r J1l1­ QCPIIHC Table. Solubility of potassium cyanide in methanol and arvcero I I CUCTeMa mROK, m KCN, r/lOO r (t, °C) r/lOO r (t, °C) KCN + Me- 1,32±O,07 3,41 ±0,04 TaHO]! (19,5) (19,5) KeN + n IH­ 5,76±0,08 19,63±O,06 uepaa (15,5) (15,5) JIHTepaTYPHble ztanHble 0 paCTBOpHMOCUI rpeumocrs 4,67 (19,5) [1, 3-5] Mr. rCpMeTUqHO 3aKpbI T bI H co B3BelllCHHbi M 06p a3QOM n OM e llJ,aJIU B rep ­ rzte rronztepzca aanacs aa­ ± 0,05 ° C . Caecs nenpepsrs no nepesteunraana B Teq eHUC 5 q npn aa­ ,n:aHHOH TeM n epal'ype . BPCM5I nepcsceum saaax 6 bIJIO onpeneneao B npezraapirr ens nsrx 3 Kc rr Cp HM CHTa x . Do UCTeqeHUU YKa3a H H OrO ap exreaa, )KH.D:KY IO ¢ a3Y 01'­ nenana OT T B ep ,n:o H C no u oms ro nporperoro no T eM­ nepar ypsr onsrra epHJI bTPa C nopncroii rrJIaCTHHKoH. B cnysae nonnor o paCTBOp CH H5I COJIH npoaozta na nOBTOpHbIH 3Kc n e p H M c HT C YMCHbiIlCHUCM COOTH O­ means KOnuqeCTB TBep,n:oH H )l(H.D:KOH ¢a3. <1> u nbTP llI01Ta ,n:OB O,n:UJIU zro nOCT05lHH OH M a CCbI B BaJ<YYMe, onpezrenas M a c cy nepacraopaaureiics T Bep ,n:o H ¢a3bI. 113 )KH.D:KOH ¢a3bI OTrOH5IJIU nozt saxyyxros« pacrso­ pUTeJIb, OCTaTOK ,n:o n O;IH UTeJIb H O Cy lliU JIU non Ba­ J<YYM0M B ar srocrbepe aprona zro rrOCT05lHHOH MaCCbI. O CT aTOK U orneneanyio raepnyio epa3Y axcrparnpo­ BaJIH 6eH30 n o M . (I13BecTHo, qTO aJIKOrOJI5IT bl uienox­ HbIX MCTaJI JIOB paCTBOpUMbI B 6eH30JIe [8, 9]). B TBep,n:oH ¢a3e aJIKOrOn5lTbI OTCYTCTBOBaJIU, B 6CH­ 30JIbHbIX 3KCTPaKTaX ax cozrepacaaae onp eaena nn B nocne npeztaapirre ns uor o ¢opMe K O H T UTp OBa H u eM, rH.D:pOJIU3a BO,n:OH : ROK + H 20 = R O H + K OH (2) K a K BH)I;HO H 3 Ta6JIU QbI, cyM MapHoe KOJlH q e­ CTBO pacrsopavux KOMnOHeHTOB COOTBCTCTBYCT JIU ­ 'reparypmaxr ,n:aHHbIM no pacTBopuMOCTU QHaHHCTOro KaJI U5I 6e3 )"ICTa 06pa30BaHU5I aJIKOr OJI5ITOB. JIHTEP ATYPA I. Gail E., Gos S., Kulzer R., Lorosch J., Rubo A., Sauer M. Inorganic Cyano Compounds. Ullmann' s Encyclopedia of Industrial Chemistry. Wcinhcim: Wiley-VCH Verlag. 2004 . 2. BaJIU 6e3 ,n:on OJIH UT CJIh H OH O'IHCTKU . 9 no­ MOCTaTUpyCMylO 51q CH KY, 24,20 (15,5) [3-5] ocymann no CTaHAa p THbIM MCTo,n:UKaM [13]. qUCTOTa pacrso­ pareneii no ,n:a H H bIM D KX COCTaBUJla 60JIee 99,8 % (cO,Ll,Cp )Ka H Ue s onu H C 60nee 0,2 %) . ~UaH H.D: KaJI U5I ((ll. ,Ll,.a .» , O AO «KoPYH,n:», r . JJ;3ep)KHHcK) UCn OJIb 30 ­ nporpersni MeTO,nOM, npeasnnana 0,1 ,n:aH Ha51 TeMrrepa Ty p a C TO'lHOCTblO KeN, r/l 00 r paCTBOpHTeJ15l (t, 0C) BCCOBbI M U3 MepCH H5I MaCChI H e O p e,n:Ba p UTeJIb H O M eTa HOJl U rJIUIJ.epUH OqUl..II,aJIU U BbIIT. o n p e,nCJI5IJIH no M CTO­ .D:Y [14]. Csreca xeraaone U rJIHQCp UHe npasenea sr B T a 6 JIu Qc . I'h ­ BeCTHO [7-12 J, qTO aJIKOrOJlU3 HCKOTOpbIX coneii cna­ . Chern. coneii opr aaaxe­ CKOM CHHTe 3e [1 J. Il pn :3T OM saaca oe anaxea a e npa­ o6pe-raKlT naa nsre 06 nx paCTBopUMOCTU B none H Opr aHHqeCKUX paCTBOpUTeJI5IX . B mrrepar ype UMe­ 44. N 9. . Comp. PaCTBopUMOCTb MeTaJIJIOB llIHpOKO UC­ nOJlb3YKlTC5I B QBCTH OH MeTaJI JIypruu H B X11MlliI 1-1 Xl1J\.1WffiCKASI TEXHOJIOrn5I 20 11 TOM 54 ssm. 9 272 p. HOBbIH crrpaao-nrax XlfMHKa U TeXIlOJIOra. OCHoBHble CBOH­ CTBa HeOpraHW!eCKHX, opraHW!eCKHX H 3JIeMeHTOOpraJ:lWIe­ CKHX coe.n:HHcHlll1 / Ilozt pen, H.K. Cxaopuos a. CIT6.: ABO HITO <<MH:p H cesrsa». 2002. 1280 c.; III - 3. 4. 5. 6. 7 . 8. 9 . ~ " ­ 10 . P la tonov A.Y u., Evdokimov A.N., Kunin A.V., Maiyor ova H.D. II J. C hern. Eng. Data . 2002. V. 47. N 5, P. 1175-1176. I !. Platonov A.Y., Kurzin A. V., Evdokimov A.N. /I J. Solution Chern. 2010. V. 39 . N 3. P . 335-342. 12. E nAoh:m fOB A.H., KYP31111 A.B., M 3HOp OB3 E.)].., Ilnaro­ HOB A.IO., C na a rcon A.A., 1.IIICToKllcTOB B.H. IIaTeHf P<!J NQ 2 178402 . 2002; Evdokimov A.N., Kunin A. V., Maiyorova E. D., Platoncs A.Yu., Sivak ov A .A., Chistokletov V.N. Patent RF ~ 2178402. 2002 (i n Russian). 13. T opnou A., cI>oPJI. P . Crryn mx XHMI1Ka . <I>113MKO-XMMWle· CKMe CBoHcTBa, MeTO.JJ:l1Kl1, 0I16JIl1orpa¢ llil. M .: MHp. 1976, 544 c.; Gordon A.J., F ord R.A. The Ch emist's Comp anion. A Handbook of Practical Data , Techniques, and References, New York: Wiley. 1972 . 423 p. 14 . llOJITOpaUKH" r .M., cI> p aH'IYK BJi., K YP311l1 A.B., EBJ\O' KHMOB A.a II 113B. By30B. XHMllil 11 XMM. TeXHOJIOfllll, 2010. T. 53 . Bsm, 3. C . 154-155; P olt or ats ki y G .M ., F r anchuk V.B., Kurzin A.V" Evdokim ov A.N. II lz v. V yssh. Uchebn. Za ved. Khim Kh im. Tekhnol. 2010. V. 53. N 3. P. 154-155 (in Russian). Ne w ha nd book for chemis t and tech nologist. M ain pro pe rties of inorganic, organic and ele rnento-organ ic co mpo unds . Ed. N.K. Skvortsov.. Saint Pe tersb urg: A NO NPO «Mi r i Se rnya». 2002 . 1280 p. (in Ru ssian). Seidell A., Linke W.F. Solub ilities of Inorganic, Metal Or ganic and O rganic Compounds. Princet on: Van Nostrand Co. 1940 .1 211 p. Koran B.li., cI>p1mMall B.M., Ka41apon B.B. Crrpaa oxaax rro paCTBOpl1MOCTIl .T . I. Kanra 1. M .- JI.: AKa.n:eMIDl a ay« CCCP. 1961. 960 c.; Kogan V.B ., Fridman V.M., Kafarov V.V. Handbook on sol ub ility. V. I. Book 1. M .- L. : Ak ade miya Nauk SS SR. 1961. 960 p. (in Russian). Stephen H., Stephen T. Solubilities of Inorgani c and Organic Compone nts. London : Pergamon Press. 1979 . 855 p. OCCCII,.JloUCKIIH A.M. II )J{P<I>XO. 1906. T. 37 . C. 1071 ­ 1074 ; Ossendovskiy A.M. II Zh. Ru ss. Fiz. Khi m. Ob sch . 190 6. V. 37 . P. 1071- 1074 (in Russian). Lod er D..J., Lee D.D. ITaTCIIT CIlIA NQ2278550. 1942; Loder D..J., Lee D.D. U.S. Patent N 2278 550 . 1942. Turova N.Ya., Novoselo va A.V. II Rus s. Chern. Rev. 1965. V. 34. N 3. P. 16 1-1 85 . Bradley D. C. II Prog. Inor g. Ch ern. 1960. V. 2. P. 303- 361. '-IaM:HO B: ztannoro cPYH K1.\I111 pOJITHOCl lJ,I1H pacr ~ eJIeHI15I ~eJIeHlliI BaJIe OT ( E HOCTb Be py, npen CI1MOCTb: f (1 3 KBa~paTI BeJI W mH norapa tp pacrrpez e Q M O)l(CT Karpezrpa ¢113wlecKoM11 KOJIJIOI1,n;HOH XI1MI1I1 e ff ( ~ l.J:TO o ~I1 a D - nonaaaa Y,ZJ;K 66.081.63+66.081.6-278 TCpB aJI «( 1.\1111 p. P(a'S.MJ c C.JI. 3 a x a p o B , A.B. Edipessoe t MCCJIE)J;OBAHI1E CEJIE KTMBHOM II OPMCTOCTM MEMli PAH C JKECT KO M CTPYKTYPo fi B I1CI1M OC T OM: ( P OCCI1HCKI-Ili XI1MI1KO-TeXHOJIOrWleCKI1H YHI1BepCI1TeT 11M. ,[1,.11. MeH,LJ;eJIeeBa) crp y CI1JIHK an CTaB JIeHl e-mail: efremov_a@bk .ru ll.HaJIbHO Pasp atiomau eeponmnocmn mii uemoo Ol(eIl KU nop u cm ocm u uaIlOljJUJl bmpat(U OHJlI1L'C U otipamu oocuomuuecuux uesttipa«. 3Kcn ep u.uelimaJI bli O nonyueuo pacnpeoeneuu e mpanc­ nopmnutx nop n o pasu epast 8 .UeAt6p aHax tta OCl106e nopucmozo cmetota. Ilpeon ascenuue meo­ pemuuecxue fjJYllKl(Ull C xopotueii mounocm uto onucu eatom nony nenu u e skcnepustenmanouue oanu ue. Krno-reas re CJJ OB a : 06paTHbIM: OCMOC, HaHOq>I1 JIbTP~IDl:, HaHOrrOpI1CTbl e MeM 6 paH bI , rrO pI1CTIUI crpy xrypa D p I1 rrOMO~I1 3a KOH a p acn p en en ean a I1cCJIe~O BaHWI xapaKTepI1CTI1K pacnpeaene­ HI15I rrop rro pas v epy B 06paTHOOCMOTWleCKI1X MeM­ 6paHax C )l( eCTl<OH CTpy KT y p OH rrpe~CTaBJI5IeT 60JIb ­ MI1 mOH n p a KTH<leCKIIH 11 HayqHblH I1HTepeC ~JI5I 60JIee HOCTSlM I1. pasvepa rrop 11 COOT BeTCT BY IOlll,I1MI1 11M HaI160JIee p a crrp o c r paaenao ii BepO~IT­ q>Op MOH MeM6paHHoro OrrI1CaHI1Sl 3aKOHa p a c n pen en en aa JIBmUOTC5I ~1I q>q>e­ [1, 2]. 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