ɋɂɇɌȿɁ ɂ ɊȿɇɌȽȿɇɈȼɋɄɈȿ ɂɁɍɑȿɇɂȿ ɌȼȿɊȾɈȽɈ ɊȺɋɌȼɈɊȺ ɄɅɂɇɈɉɂɊɈɄɋȿɇɈȼ ɊəȾȺ ɗȽɂɊɂɇ-ȽȿȾȿɇȻȿɊȽɂɌ ɌȺɌɖəɇȺ ɄɈȼȺɅɖɋɄȺə, ȺɇȾɊȿɃ ɄɈȼȺɅɖɋɄɂɃ, ȺɅȿɄɋȿɃ ɄɈɌȿɅɖɇɂɄɈȼ ɂɧɫɬɢɬɭɬ ɷɤɫɩɟɪɢɦɟɧɬɚɥɶɧɨɣ ɦɢɧɟɪɚɥɨɝɢɢ ɊȺɇ,142432, Ɇɨɫɤɨɜɫɤɚɹ ɨɛɥ., ɝ.ɑɟɪɧɨɝɨɥɨɜɤɚ, ɂɧɫɬɢɬɭɬɫɤɚɹ ɭɥ., ɞ.4. e-mail: tatiana76@iem.ac.ru, ɬɟɥ./ɮɚɤɫ: 7(49652)44425 Abstract With the purpose of definition of thermodynamic functions of mixing, synthesis of hedenbergite - aegirine solid solutions was carried out. High pressure cold-seal hydrothermal vessels with external heating were used in experiments. Synthesis of hedenbergite was carried out at Ɍ=600 and 700qɋ and Ɋ=1 and 2 kbar. Aegirine was synthesized in wide interval of parameters: Ɍ=450 and 750qɋ, Ɋ=1-1.5 kbar and duration 31 day. Solid solutions of clinopyroxenes were synthesized at Ɍ=650qɋ and Ɋ=2 kbar. The stability of oxygen potential during experiences was supervised by a buffer mixtures iron + wustite, graphite, Ni + NiO, magnetite + hematite. Products of experiences on synthesis of solid solution Hed-Aeg are represented by the lengthened brown crystals of (20-50 microns). We studied the synthesized hedenbergite-aegirine solid solutions by X-ray. Calculation of unit cell parameters of pure hedenbergite and aegirine has shown their conformity to the data of PDF-2 database. We approximated concentration correlations of unit cell parameters of hedenbergite - aegirine solid solutions. On the basis of unit cell parameters changing one can consider that hedenbergite - aegirine solid solution is close to ideal. Ɋɟɡɸɦɟ ɋɢɧɬɟɡ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɜ ɪɹɞɭ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɨɜɟɞɟɧ ɫ ɢɫɩɨɥɶɡɨɜɚɧɢɟɦ ɝɢɞɪɨɬɟɪɦɚɥɶɧɵɯ ɭɫɬɚɧɨɜɨɤ ɫ ɜɧɟɲɧɢɦ ɧɚɝɪɟɜɨɦ ɢ ɯɨɥɨɞɧɵɦ ɡɚɬɜɨɪɨɦ ɜ ɡɨɥɨɬɵɯ ɚɦɩɭɥɚɯ. ȼ ɤɚɱɟɫɬɜɟ ɤɢɫɥɨɪɨɞɧɵɯ ɛɭɮɟɪɨɜ ɜ ɨɩɵɬɚɯ ɩɪɢɦɟɧɹɥɢɫɶ ɫɦɟɫɢ ɠɟɥɟɡɨ+ɜɸɫɬɢɬ, ɝɪɚɮɢɬ, Ni+NiO, ɦɚɝɧɟɬɢɬ+ɝɟɦɚɬɢɬ. ɋɢɧɬɟɡ ɝɟɞɟɧɛɟɪɝɢɬɚ ɩɪɨɜɨɞɢɥɫɹ ɩɪɢ Ɍ=600 ɢ 700qɋ ɢ Ɋ=1 ɢ 2 ɤɛɚɪ. ɗɝɢɪɢɧɵ ɩɨɥɭɱɟɧɵ ɜ ɲɢɪɨɤɨɦ ɢɧɬɟɪɜɚɥɟ ɩɚɪɚɦɟɬɪɨɜ: Ɍ=450 ɢ 750qɋ ɢ Ɋ=1-1.5 ɤɛɚɪ. Ɍɜɟɪɞɵɟ ɪɚɫɬɜɨɪɵ ɩɢɪɨɤɫɟɧɨɜ ɫɢɧɬɟɡɢɪɨɜɚɧɵ ɩɪɢ Ɍ=650qɋ ɢ Ɋ=2 ɤɛɚɪ. Ɇɢɤɪɨɡɨɧɞɨɜɵɣ ɚɧɚɥɢɡ ɩɪɨɞɭɤɬɨɜ ɨɩɵɬɨɜ ɩɨɤɚɡɚɥ ɨɞɧɨɪɨɞɧɨɫɬɶ ɫɢɧɬɟɬɢɱɟɫɤɢɯ ɨɛɪɚɡɰɨɜ ɢ ɩɪɚɤɬɢɱɟɫɤɢ ɩɨɥɧɨɟ ɫɨɨɬɜɟɬɫɬɜɢɟ ɤɪɢɫɬɚɥɥɨɯɢɦɢɱɟɫɤɢɦ ɮɨɪɦɭɥɚɦ. ɉɨ ɧɚɲɢɦ ɨɩɵɬɧɵɦ ɞɚɧɧɵɦ ɬɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɝɟɞɟɧɛɟɪɝɢɬ - ɷɝɢɪɢɧ ɫɭɳɟɫɬɜɭɟɬ ɩɪɢ 650qɋ ɢ Ɋ=2 ɤɛɚɪ ɛɟɡ ɪɚɡɪɵɜɚ ɫɦɟɫɢɦɨɫɬɢ. Ⱦɥɹ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɨɜɟɞɟɧɨ ɪɟɧɬɝɟɧɨɜɫɤɨɟ ɢɡɭɱɟɧɢɟ ɢ ɭɬɨɱɧɟɧɵ ɩɚɪɚɦɟɬɪɵ ɢɯ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ. Ɋɚɫɱɟɬ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɤɨɧɟɱɧɵɯ ɦɢɧɚɥɨɜ ɩɨɤɚɡɚɥ ɢɯ ɫɨɨɬɜɟɬɫɬɜɢɟ ɞɚɧɧɵɦ, ɩɪɢɜɟɞɟɧɧɵɦ ɜ ɤɚɪɬɨɬɟɤɟ PDF-2. ɇɚ ɨɫɧɨɜɟ ɚɧɚɥɢɡɚ ɢɡɦɟɧɟɧɢɹ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɨɤɚɡɚɧɨ, ɱɬɨ ɬɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɛɥɢɡɨɤ ɤ ɢɞɟɚɥɶɧɨɦɭ. Ʉɥɢɧɨɩɢɪɨɤɫɟɧɵ ɪɹɞɚ ɞɢɨɩɫɢɞ – ɝɟɞɟɧɛɟɪɝɢɬ - ɷɝɢɪɢɧ ɨɞɧɢ ɢɡ ɧɚɢɛɨɥɟɟ ɪɚɫɩɪɨɫɬɪɚɧɟɧɧɵɯ ɦɢɧɟɪɚɥɨɜ ɜ ɩɨɪɨɞɚɯ ɳɟɥɨɱɧɵɯ ɤɨɦɩɥɟɤɫɨɜ (Ʌɨɜɨɡɟɪɫɤɢɣ, Ɍɢɤɲɟɨɡɟɪɫɤɢɣ, ɏɢɛɢɧɫɤɢɣ ɦɚɫɫɢɜɵ ɢ ɞɪ.). Ɉɞɧɚɤɨ ɨɬɫɭɬɫɬɜɢɟ ɞɚɧɧɵɯ ɩɨ ɬɟɪɦɨɞɢɧɚɦɢɤɟ ɷɬɢɯ ɦɢɧɟɪɚɥɨɜ ɧɟ ɞɚɟɬ ɜɨɡɦɨɠɧɨɫɬɶ ɜ ɩɨɥɧɨɣ ɦɟɪɟ ɢɫɩɨɥɶɡɨɜɚɬɶ ɪɚɡɥɢɱɧɵɟ ɝɟɨɬɟɪɦɨɦɟɬɪɵ ɞɥɹ ɨɩɪɟɞɟɥɟɧɢɹ ɭɫɥɨɜɢɣ ɮɨɪɦɢɪɨɜɚɧɢɹ ɬɟɯ ɢɥɢ ɢɧɵɯ ɩɨɪɨɞ. Ⱦɥɹ ɨɩɪɟɞɟɥɟɧɢɹ ɬɟɪɦɨɞɢɧɚɦɢɱɟɫɤɢɯ ɮɭɧɤɰɢɣ ɫɦɟɲɟɧɢɹ ɩɢɪɨɤɫɟɧɨɜ ɩɪɨɜɟɞɟɧ ɫɢɧɬɟɡ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɜ ɪɹɞɭ ɝɟɞɟɧɛɟɪɝɢɬ - ɷɝɢɪɢɧ. Ⱦɥɹ ɩɪɨɜɟɞɟɧɢɹ ɷɤɫɩɟɪɢɦɟɧɬɨɜ ɢɫɩɨɥɶɡɨɜɚɧɵ ɝɢɞɪɨɬɟɪɦɚɥɶɧɵɟ ɭɫɬɚɧɨɜɤɢ ɫ ɜɧɟɲɧɢɦ ɧɚɝɪɟɜɨɦ ɢ ɯɨɥɨɞɧɵɦ ɡɚɬɜɨɪɨɦ. ɋɢɧɬɟɡ ɝɟɞɟɧɛɟɪɝɢɬɚ ɩɪɨɜɨɞɢɥɫɹ ɩɪɢ Ɍ=600 ɢ 700qɋ ɢ Ɋ=1 ɢ 2 ɤɛɚɪ, ɞɥɢɬɟɥɶɧɨɫɬɶ ɨɩɵɬɨɜ ɫɨɫɬɚɜɢɥɚ 27 ɢ 21 ɫɭɬɤɢ ɫɨɨɬɜɟɬɫɬɜɟɧɧɨ. ɗɝɢɪɢɧɵ ɩɨɥɭɱɟɧɵ ɜ ɲɢɪɨɤɨɦ ɢɧɬɟɪɜɚɥɟ ɩɚɪɚɦɟɬɪɨɜ: Ɍ=450 ɢ 750qɋ ɢ Ɋ=1-1.5 ɤɛɚɪ ɩɪɢ ɞɥɢɬɟɥɶɧɨɫɬɢ 31 ɫɭɬɤɢ. Ɍɜɟɪɞɵɟ ɪɚɫɬɜɨɪɵ ɩɢɪɨɤɫɟɧɨɜ ɫɢɧɬɟɡɢɪɨɜɚɥɢɫɶ ɩɪɢ Ɍ=650qɋ ɢ Ɋ=2 ɤɛɚɪ, ɞɥɢɬɟɥɶɧɨɫɬɶ ɨɩɵɬɨɜ - 21 ɫɭɬɤɢ. ɂɫɯɨɞɧɵɦɢ ɦɚɬɟɪɢɚɥɚɦɢ ɞɥɹ ɫɢɧɬɟɡɚ ɤɨɧɟɱɧɵɯ ɱɥɟɧɨɜ ɪɹɞɚ (ɝɟɞɟɧɛɟɪɝɢɬɚ ɢ ɷɝɢɪɢɧɚ) ɫɥɭɠɢɥɢ ɝɟɥɟɜɵɟ ɫɦɟɫɢ ɫɨɨɬɜɟɬɫɬɜɭɸɳɢɯ ɫɨɫɬɚɜɨɜ (ɜ ɬɨɦ ɱɢɫɥɟ ɩɪɟɞɜɚɪɢɬɟɥɶɧɨ ɜɨɫɫɬɚɧɨɜɥɟɧɧɵɟ ɜ ɫɪɟɞɟ ɜɨɞɨɪɨɞɚ ɜ ɬɟɱɟɧɢɟ 2-3 ɱɚɫɨɜ ɩɪɢ ɬɟɦɩɟɪɚɬɭɪɟ 550qɋ), ɚ ɞɥɹ ɩɨɥɭɱɟɧɢɹ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ - ɦɟɯɚɧɢɱɟɫɤɢɟ ɫɦɟɫɢ ɪɚɧɟɟ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɝɟɞɟɧɛɟɪɝɢɬɚ (ɢɡ ɨɩɵɬɨɜ 5844ɚ, 5844ɛ ɢ 5889) ɢ ɷɝɢɪɢɧɚ (ɢɡ ɨɩɵɬɚ 5799). Ɉɩɵɬɵ ɩɨ ɫɢɧɬɟɡɭ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɩɪɨɜɨɞɢɥɢ ɜ ɡɨɥɨɬɵɯ ɚɦɩɭɥɚɯ. Ⱦɥɹ ɩɨɞɟɪɠɚɧɢɹ ɩɨɫɬɨɹɧɫɬɜɚ ɩɨɬɟɧɰɢɚɥɚ ɤɢɫɥɨɪɨɞɚ ɜ ɡɚɜɢɫɢɦɨɫɬɢ ɨɬ ɨɤɢɫɥɢɬɟɥɶɧɵɯ ɭɫɥɨɜɢɣ ɜ ɨɩɵɬɚɯ ɢɫɩɨɥɶɡɨɜɚɥɢɫɶ ɫɦɟɫɢ ɥɢɛɨ ɠɟɥɟɡɨ+ɜɸɫɬɢɬ, ɝɪɚɮɢɬ, Ni+NiO, ɦɚɝɧɟɬɢɬ+ɝɟɦɚɬɢɬ, ɩɨɦɟɳɟɧɧɵɟ ɜɨ ɜɧɭɬɪɟɧɧɸɸ ɩɥɚɬɢɧɨɜɭɸ ɚɦɩɭɥɭ, ɥɢɛɨ ɝɪɚɮɢɬ ɫɩɟɤɬɪɚɥɶɧɨɣ ɱɢɫɬɨɬɵ, ɩɨɦɟɳɟɧɧɵɣ ɧɟɩɨɫɪɟɞɫɬɜɟɧɧɨ ɜ ɪɟɚɤɰɢɨɧɧɭɸ ɫɦɟɫɶ. ɋɨɨɬɧɨɲɟɧɢɟ ɧɚɜɟɫɤɚ/ɮɥɸɢɞ ɫɨɫɬɚɜɥɹɥɨ 10:1. ɉɨɫɥɟ ɨɩɵɬɚ ɫɨɫɬɚɜ ɬɜɟɪɞɵɯ ɩɪɨɞɭɤɬɨɜ ɨɩɪɟɞɟɥɹɥɫɹ ɦɟɬɨɞɨɦ ɪɟɧɬɝɟɧɨɫɩɟɤɬɪɚɥɶɧɨɝɨ ɦɢɤɪɨɚɧɚɥɢɡɚ. ɇɚ ɨɫɧɨɜɟ 235 ɪɟɧɬɝɟɧɨɜɫɤɢɯ ɞɚɧɧɵɯ ɭɬɨɱɧɹɥɢɫɶ ɩɚɪɚɦɟɬɪɵ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɤɥɢɧɨɩɢɪɨɤɫɟɧɨɜ. ɉɪɨɞɭɤɬɵ ɨɩɵɬɨɜ ɩɨ ɫɢɧɬɟɡɭ ɬɜɟɪɞɨɝɨ ɪɚɫɬɜɨɪɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɟɞɫɬɚɜɥɹɥɢ ɫɨɛɨɣ ɦɚɫɫɭ ɭɞɥɢɧɟɧɧɵɯ ɤɪɢɫɬɚɥɥɨɜ ɤɥɢɧɨɩɢɪɨɤɫɟɧɨɜ (ɪɚɡɦɟɪ ɤɪɢɫɬɚɥɥɢɬɨɜ 20-50 ɦɤɦ), ɛɭɪɨ-ɤɨɪɢɱɧɟɜɨɝɨ ɰɜɟɬɚ. Ɇɢɤɪɨɡɨɧɞɨɜɵɣ ɚɧɚɥɢɡ ɩɨɤɚɡɚɥ ɨɞɧɨɪɨɞɧɨɫɬɶ ɫɢɧɬɟɬɢɱɟɫɤɢɯ ɨɛɪɚɡɰɨɜ (ɜɚɪɢɚɰɢɹ ɫɨɫɬɚɜɨɜ ɜ ɩɪɟɞɟɥɚɯ ɨɞɧɨɝɨ ɨɛɪɚɡɰɚ ɧɟ ɩɪɟɜɵɲɚɥɚ 5 ɦɨɥ.%) ɢ ɩɪɚɤɬɢɱɟɫɤɢ ɩɨɥɧɨɟ ɫɨɨɬɜɟɬɫɬɜɢɟ ɤɪɢɫɬɚɥɥɨɯɢɦɢɱɟɫɤɢɦ ɮɨɪɦɭɥɚɦ (Ɍɚɛɥ. 1). ȼ ɧɟɫɤɨɥɶɤɢɯ ɨɩɵɬɚɯ ɜ ɤɚɱɟɫɬɜɟ ɩɪɢɦɟɫɧɨɣ ɮɚɡɵ ɞɢɚɝɧɨɫɬɢɪɨɜɚɧ ɤɜɚɪɰ (Ɋɢɫ. 1ɚ, ɛ). ɋɥɟɞɭɟɬ ɨɬɦɟɬɢɬɶ, ɱɬɨ ɫɨɫɬɚɜɵ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɫɞɜɢɧɭɥɢɫɶ ɨɬɧɨɫɢɬɟɥɶɧɨ ɡɚɞɚɧɧɵɯ ɢɡɧɚɱɚɥɶɧɨ ɫɬɚɪɬɨɜɵɦɢ ɫɦɟɫɹɦɢ ɜ ɫɬɨɪɨɧɭ ɭɜɟɥɢɱɟɧɢɹ ɫɨɞɟɪɠɚɧɢɹ ɷɝɢɪɢɧɨɜɨɝɨ ɦɢɧɚɥɚ ɜ ɤɚɠɞɨɦ ɨɩɵɬɟ. Qz Cpx Cpx Cpx Ɋɢɫ. 1ɚ. ɉɪɨɞɭɤɬɵ ɨɩɵɬɚ 5941. ɋɪɟɞɧɢɣ ɫɨɫɬɚɜ Ɋɢɫ. 1ɛ. ɉɪɨɞɭɤɬɵ ɨɩɵɬɚ 5944. ɋɪɟɞɧɢɣ ɫɨɫɬɚɜ ɩɨɥɭɱɟɧɧɵɯ ɤɥɢɧɨɩɢɪɨɤɫɟɧɨɜ ɩɨɥɭɱɟɧɧɵɯ ɤɥɢɧɨɩɢɪɨɤɫɟɧɨɜ Na0.18Ca0.78Fe2+0.81Fe3+0.28Si1.95O5.86 . Na0.72Ca0.28Fe2+0.21Fe3+0.86Si1.93O5.57 . Ɍɚɤɢɦ ɨɛɪɚɡɨɦ, ɩɨ ɧɚɲɢɦ ɨɩɵɬɧɵɦ ɞɚɧɧɵɦ ɬɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɝɟɞɟɧɛɟɪɝɢɬ - ɷɝɢɪɢɧ ɫɭɳɟɫɬɜɭɟɬ ɩɪɢ 650qɋ ɢ Ɋ=2 ɤɛɚɪ ɛɟɡ ɪɚɡɪɵɜɚ ɫɦɟɫɢɦɨɫɬɢ. ɋɢɧɬɟɡ ɧɟɩɪɟɪɵɜɧɨɝɨ ɪɹɞɚ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɬɚɤɠɟ ɨɩɢɫɚɧ ɜ ɫɬɚɬɶɟ Redhammer et. ɚl 2006, ɜ ɤɨɬɨɪɨɣ ɩɪɨɜɟɞɟɧ ɫɢɧɬɟɡ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɢ Ɍ=1200-1400qɋ ɢ Ɋ=30-40 ɤɛɚɪ. Ɍɚɛɥɢɰɚ 1. ɋɪɟɞɧɢɟ ɫɨɫɬɚɜɵ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɤɥɢɧɨɩɢɪɨɤɫɟɧɨɜ (ɩɨ ʋ ɨɩɵɬɨɜ). DzȘȐșȚȈȓȓȖȝȐȔȐȟȍșȒȈȧ ȜȖȘȔțȓȈ 5941 5942 5943 5944 Si 1.95 1.93 1.96 1.93 2+ Fe 0.81 0.50 0.44 0.21 Fe3+ 0.28 0.57 0.60 0.86 Ca 0.78 0.55 0.47 0.28 Na 0.18 0.44 0.53 0.72 O 5.86 5.71 5.70 5.57 XAeg 0.24 0.51 0.56 0.79 XAeg – ɦɨɥɶɧɚɹ ɞɨɥɹ ɧɚɬɪɢɹ (ɷɝɢɪɢɧɚ) ɜ ɬɜɟɪɞɨɦ ɪɚɫɬɜɨɪɟ. 236 ɉɨ ɞɚɧɧɵɦ ɪɟɧɬɝɟɧɨɜɫɤɨɝɨ ɢɡɭɱɟɧɢɹ ɭɬɨɱɧɟɧɵ ɩɚɪɚɦɟɬɪɵ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɬɜɟɪɞɨɝɨ ɪɚɫɬɜɨɪɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ. Ⱦɥɹ ɫɢɧɬɟɡɢɪɨɜɚɧɧɵɯ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɨɜɟɞɟɧɨ ɪɟɧɬɝɟɧɨɜɫɤɨɟ ɢɡɭɱɟɧɢɟ ɧɚ ɞɢɮɪɚɤɬɨɦɟɬɪɟ HZG-4 ɜ ɪɟɠɢɦɟ ɩɨɫɬɨɹɧɧɨɝɨ ɫɤɚɧɢɪɨɜɚɧɢɹ. ȼ ɤɚɱɟɫɬɜɟ ɜɧɭɬɪɟɧɧɟɝɨ ɫɬɚɧɞɚɪɬɚ ɩɪɢɦɟɧɹɥɫɹ ɤɪɟɦɧɢɣ ɫɩɟɤɬɪɚɥɶɧɨɣ ɱɢɫɬɨɬɵ (ɚ=5.4307 [A]). ɍɝɥɨɜɵɟ ɩɨɥɨɠɟɧɢɹ ɨɬɪɚɠɟɧɢɣ ɭɬɨɱɧɹɥɢɫɶ ɦɟɬɨɞɨɦ ɩɨɥɢɝɨɧɚɥɶɧɨɣ ɤɨɪɪɟɤɰɢɢ ɫ ɢɫɩɨɥɶɡɨɜɚɧɢɟɦ ɩɪɨɝɪɚɦɦɵ SPECTR. Ɋɚɫɱɟɬ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɤɨɧɟɱɧɵɯ ɦɢɧɚɥɨɜ – ɝɟɞɟɧɛɟɪɝɢɬɚ ɢ ɷɝɢɪɢɧɚ ɩɨɤɚɡɚɥ ɢɯ ɫɨɨɬɜɟɬɫɬɜɢɟ ɞɚɧɧɵɦ, ɩɪɢɜɟɞɟɧɧɵɦ ɜ ɤɚɪɬɨɬɟɤɟ PDF-2. Ⱦɚɧɧɵɟ ɧɚɫɬɨɹɳɟɣ ɪɚɛɨɬɵ ɩɨ ɩɚɪɚɦɟɬɪɚɦ ɬɜɟɪɞɵɯ ɪɚɫɬɜɨɪɨɜ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɪɟɞɫɬɚɜɥɟɧɵ ɧɚ ɪɢɫɭɧɤɟ 2 ɢ ɜ ɬɚɛɥɢɰɟ 2 ɢ ɛɥɢɡɤɢ ɤ ɪɟɡɭɥɶɬɚɬɚɦ, ɩɨɥɭɱɟɧɧɵɦ Redhammer et al. 2006. Ɍɚɛɥɢɰɚ 2. ɉɚɪɚɦɟɬɪɵ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɬɜɟɪɞɨɝɨ ɪɚɫɬɜɨɪɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ (XAeg - ɦɨɥɶɧɚɹ ɞɨɥɹ ɧɚɬɪɢɹ (ɷɝɢɪɢɧɚ) ɜ ɬɜɟɪɞɨɦ ɪɚɫɬɜɨɪɟ). ʋ ɨɩɵɬɚ XAeg a, [A] b, [A] c, [A] ȕ, [o] V, [A3] 5844a 5844b 5889 5941 5942 5943 5944 5799 5633 0 0 0 0.24 0.51 0.56 0.79 1 1 9.020(1) 9.019(1) 9.023(1) 8.967(1) 8.926(1) 8.903(1) 8.851(1) 8.794(2) 8.797(1) 5.250(1) 5.249(1) 5.248(1) 5.253(1) 5.261(1) 5.274(1) 5.280(2) 5.290(1) 5.296(1) 104.80(1) 104.79(1) 104.83(1) 105.39(1) 105.78(1) 106.15(1) 106.44(2) 107.42(1) 107.41(1) 450.8(1) 450.9(1) 450.7(1) 444.9(1) 441.7(1) 440.1(1) 436.1(3) 428.4(1) 429.3(1) 9.847(1) 9.851(1) 9.846(1) 9.797(1) 9.775(1) 9.757(1) 9.728(3) 9.650(1) 9.658(1) Ʉɨɥ-ɜɨ ɨɬɪɚɠɟɧɢɣ 30 26 31 32 29 33 19 26 36 ɇɟɤɨɬɨɪɨɟ ɪɚɡɥɢɱɢɟ ɩɚɪɚɦɟɬɪɨɜ, ɭɬɨɱɧɟɧɧɵɯ ɧɚɦɢ ɢ ɩɪɢɜɟɞɟɧɧɵɯ ɜ ɥɢɬɟɪɚɬɭɪɟ ɦɨɠɧɨ ɨɛɴɹɫɧɢɬɶ ɫɭɳɟɫɬɜɟɧɧɨ ɪɚɡɧɵɦɢ ɭɫɥɨɜɢɹɦɢ ɫɢɧɬɟɡɚ ɨɛɪɚɡɰɨɜ ɞɥɹ ɢɫɫɥɟɞɨɜɚɧɢɹ. 10.00 108.0 0 a, [A] 9.90 107.0 9.80 9.70 9.60 0.0 9.10 1 2 3 E>@ 0 106.0 0.2 0.4 0.6 0.8 1.0 0 b, [A] 9.00 105.0 104.0 0.0 8.90 0.2 0.4 0.6 8.80 8.70 0.0 5.50 0.8 1.0 0 V, [A3] 0.2 0.4 0.6 0.8 1.0 450.0 0 c, [A] 5.40 5.30 5.20 5.10 0.0 425.0 0.2 0.4 0.6 Cpx XAeg 0.8 1.0 0.0 0.2 0.4 0.6 Cpx XAeg 0.8 1.0 Ɋɢɫ. 2. ɉɚɪɚɦɟɬɪɵ ɷɥɟɦɟɧɬɚɪɧɨɣ ɹɱɟɣɤɢ ɬɜɟɪɞɨɝɨ ɪɚɫɬɜɨɪɚ ɝɟɞɟɧɛɟɪɝɢɬ-ɷɝɢɪɢɧ ɩɨ ɞɚɧɧɵɦ: 1 ɧɚɫɬɨɹɳɟɣ ɪɚɛɨɬɵ; 2 - Redhammer et. al., 2006, 3 - ɚɩɩɪɨɤɫɢɦɚɰɢɹ ɞɚɧɧɵɯ Redhammer et. al., 2006. 237 Ʉɨɧɰɟɧɬɪɚɰɢɨɧɧɵɟ ɡɚɜɢɫɢɦɨɫɬɢ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɬɜɟɪɞɨɝɨ ɪɚɫɬɜɨɪɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɚɩɩɪɨɤɫɢɦɢɪɭɸɬɫɹ ɫɥɟɞɭɸɳɢɦɢ ɭɪɚɜɧɟɧɢɹɦɢ: a = 9.84497 - 0.104972 · XAeg - 0.0823278 · XAeg)2 [A]; b = 9.02214 - 0.183327 · XAeg - 0.0433729 · XAeg)2 [A]; c = 5.24777 + 0.0233369 · XAeg + 0.0225974 · XAeg)2 [A]; ȕ = 104.827 + 1.53415 · XAeg + 1.01039 · XAeg)2 [°]; V = 450.595 - 14.991 · XAeg - 6.44665 · (XAeg)2 [A3]; ɝɞɟ XAeg - ɦɨɥɶɧɚɹ ɞɨɥɹ ɧɚɬɪɢɹ (ɷɝɢɪɢɧɚ) ɜ ɬɜɟɪɞɨɦ ɪɚɫɬɜɨɪɟ. ɇɚ ɨɫɧɨɜɟ ɚɧɚɥɢɡɚ ɢɡɦɟɧɟɧɢɹ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɤɥɢɧɨɩɢɪɨɤɫɧɨɜ ɪɹɞɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɩɨɤɚɡɚɧɨ, ɱɬɨ ɬɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɛɥɢɡɨɤ ɤ ɢɞɟɚɥɶɧɨɦɭ. ȼɵɜɨɞɵ 1. ȼ ɲɢɪɨɤɨɦ ɢɧɬɟɪɜɚɥɟ ɩɚɪɚɦɟɬɪɨɜ ɫɢɧɬɟɡɢɪɨɜɚɧɵ ɩɢɪɨɤɫɟɧɵ ɪɹɞɚ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ, ɭɬɨɱɧɟɧɵ ɩɚɪɚɦɟɬɪɵ ɢɯ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɢ ɜɵɜɟɞɟɧɵ ɤɨɧɰɟɧɬɪɚɰɢɨɧɧɵɟ ɡɚɜɢɫɢɦɨɫɬɢ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ. 2. Ɍɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɝɟɞɟɧɛɟɪɝɢɬ - ɷɝɢɪɢɧ ɫɭɳɟɫɬɜɭɟɬ ɩɪɢ 650qɋ ɢ Ɋ=2 ɤɛɚɪ ɛɟɡ ɪɚɡɪɵɜɚ ɫɦɟɫɢɦɨɫɬɢ. 3. ɇɚ ɨɫɧɨɜɟ ɚɧɚɥɢɡɚ ɢɡɦɟɧɟɧɢɹ ɩɚɪɚɦɟɬɪɨɜ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ, ɬɜɟɪɞɵɣ ɪɚɫɬɜɨɪ ɝɟɞɟɧɛɟɪɝɢɬ – ɷɝɢɪɢɧ ɛɥɢɡɨɤ ɤ ɢɞɟɚɥɶɧɨɦɭ. Ɋɚɛɨɬɚ ɜɵɩɨɥɧɟɧɚ ɩɪɢ ɩɨɞɞɟɪɠɤɟ ɊɎɎɂ, ɝɪɚɧɬɵ ʋ 06-05-64904, 07-05-00217; ɝɪɚɧɬɨɜ ɉɪɟɡɢɞɟɧɬɚ ɊɎ ɆɄ-2948.2006.5, ɆɄ-3499.2006.5 ɢ Ɏɨɧɞɚ ɫɨɞɟɣɫɬɜɢɹ ɨɬɟɱɟɫɬɜɟɧɧɨɣ ɧɚɭɤɟ. ɅɂɌȿɊȺɌɍɊȺ: 1. Redhammer G.J., Amthauer G., Roth G., Tippelt G., Lottermoser W. Single-crystal X-ray diffraction and temperature dependent 57Fe Mössbauer spectroscopy on the hedenbergite-aegirine (Ca,Na)(Fe2+,Fe3+)Si2O6 solid solution. //Amer. Mineral., 2006,V. 91, pp. 1271-1292. 238