Ы : 577.1 541.128 , , lta 4455@yandex.ru ы - Ы Ы. , , . Active centre, activated complex, internal effect of electron transfer. я . - , . , . : Fe3+, , . Fe3+ . - [1–3]. . . , . , , , – Ko A CO2 . , , 240 - CO2 ( ). + ; , ; – SKo A. + / , - , [1]. . , , – . O C H3C COOH : K = 3,162 10–3. . . Fe3+. – - , . ( 5) P-450 , . - S2–, - . . , . Fe3+. . Fe3+ - . D- L- – 2 ( · 2) + O2 [1]: ( )+ 2 2. 241 , , - . , . [1]. , . . . - , - . : H2O2 H2O 0,5. pH (4–9) 30 °C [4]. . .1 . . . . . 1. 242 - я - . Philadelphus Coronarius L [5] . , , (50 ) , [5]. - , . . . - . .Э UV-2401 PC. 1 , . , 400 - [6]. . 400–500 Fe – N: , - λ1 = 430 ; E = 280 / ; λ2 = 460 ; E = 270 / , – Э FeN. , ( . ), (III) [7, 8]. Fe3+ 3d5 – - . 243 4s-, 4p- , . . 3d. - COOH CO . Э : 30 , 0,80 Fe3+; / / [7, 8]. 400–500 Fe–N, Fe N . FeN Fe3+ , , - . Fe3+ FeN . - Fe FeN . Fe N FeN . . , Fe , Fe3+ N FeN. FeN - . H2O2 - FeN. H2O2 FeN. H2O2 FeN. ( - ) Fe–O N–O. H2O2 FeN. 244 . 2. . 2. H2O2 FeN. Fe – N (2,10 Å) O – O (1,48 Å) ( .2 ) FeN [6] H2O2 . , 109°. , Fe N FeN H2O2. H2O2 . - O FeN , - .2 FeN H2O2 FeN, . , H2O2 FeN . - . , , H2O2, pH . . , , FeN , - . . +3. 6. (III) , – OOH¯; . 245 FeN +e, Fe - N– – e. . FeN FeN. FeN O. O – 1 . O O –1 - . Fe–O N–O , . FeN H2O2. , FeN H2O2 FeN. – , FeN . , , . , - , H2O2 FeN. . . ., Ш 1. 638 . 2. . 3. .: 4. . . 246 - . .Н. : . . . : . 2. .: . ., 1986. 505 . . ., . . , 2008. 124 . . . . 2. .: . ., 1988. 391 . . .: ., , 2004. . . . : . И. . 5. 6. . . , 1976. 142 . 7. И. . . . XII . . . . 2008. . 236–237. 8. И. . . . . 2007. . 293–394. , H2O2 // - . : - ». 1994. № 2. . 108–110. « . : . .: : . FeN . H2O2 FeN .: . . XI . . - . *** Is found that FeN group of atoms of porphyrinic nucleus is an active centre of the catalase molecule. Internal effect of electron transfer in the activated complex H2O2 FeN represents a mechanism decomposion reaction of H2O2 by catalase. 247