ВЛИЯНИЕ МЕЖДОУЗЕЛЬНЫХ МОЛЕКУЛ ВОДОРОДА И

01.04.07 –
ё
-
– 2015
.
. .
:
-
,
-
,
:
,
-
,
-
. . .
я
ё
я:
«
. .
»,
. .
« 4 »
125009,
.
2015
Э
. . .
, . 11,
. 7.
-
(
.
)
12:30
.
Э
.
http://www.cplire.ru/rus/dissertations.html
«….»
2015 .
ё
,
-
,
. .
Щ
.
[1]
[2].
ё
.
Д3,4],
,
.
[5, 6]
,
(
-
)
[7].
,
.
,
,
.
.
Ц
ё
.
,
,
,
SPCVD1 [8].
,
Yb3+
Er3+
4f
,
.
:
1
SPCVD – surface plasma chemical vapor deposition (по е
а ы)
3
о т ое пла
е
ое о а де
е
а о о
ё
1.
,
,
,
,
80 – 900 K.
,
2.
,
H2
D2 .
3.
.
я
.
,
,
,
,
,
.
.
,
,
.
,
,
ё
.
,
.
,
,
.
4
я
.
.
,
.
,
,
.
я,
.
,
1.
,
,
.
,
(
, R. Kohlrausch [9]).
,
.
2.
,
,
.
,
.
,
,
,
5
.
з100 K,
H2
D2 .
,
3.
,
3.5
,
.% Al2O3,
,
.
,
.
.
4.
«
»
1.42
,
.
.
я
.
: 36ECOC-2010 (
,
Laser Optics (
(
(
, 2010 .), 14, 2010
-
, 2011 .), III-
, 2011), 9-
Dielectrics and Related Devices (
.), 53Advanced
,
, 2012), II,(
ICG
-
2013 (
,
, 2013 .),
,
2013),
OFC-2013 (
-
, 2013).
6
: «
Crystalline Solids» (3
», «
), Optics Express.
6
», «Journal of Non-
.
,
№ 191
.
Э
.
. .
,
,
,
.
,
.
ё
.
,
,
2
, 19
114
ё
,
.
53
.
123
,
.
,
,
.
,
.
.
,
ё
,
.
,
.
,
,
[5].
,
,
.
2
,
,
.
,
,
.
SPCVD [8].
7
,
,
1
.
2.
1.
ё
ё
.
#1
SiO2 + Bi
#2
SiO2 + Bi
#3
SiO2 + Al + Bi
#4
SiO2 + Al + Bi
#1
#3
.
#2
#4
.
-
#5 – #9 (
.
2).
2.
.
,
, wt.%
-3
*10
808
(
20
#5
Bi
0
< 0.1
19.7
#6
Bi
0.52
< 0.1
35.8
#7
Bi
3.12
< 0.1
15.0
#8
Yb
0
0.17
-
#9
Er
0
1.56
-
Д / ]
5, 6, 7)
.
-4
.
InGaAs
980
1
808
,
-
Tektronics DPO3012.
8
,
.
50%
(
.1).
«1»
,
«2»,
«3».
ё
.
,
100 – 120
300 – 900 K.
[12]
.
.1
.
3
ё
Yb3+ (
Er3+
,
#8, #9).
(4I13/2→4I15/2
2
F5/2→2F7/2
).
.2
.
[10].
.
,
,
«
»,
[9] (
(1)
� –
, � � –
. 2 ):
� � = � exp[ − �⁄� � ],
,� –
9
, � –
,
, �<1 –
,
.
. 2.
Er3+ a, b, c
,
Yb3+ b, c,
.

(
. 2 c).
.
.3
Er3+
Yb3+
.
(
(
. 3).
. 3 a),
(
10
. 3 b).
(
. 3 c).
,
,
ё
ё
.
β(1000/T)
(
“ill problem” [11]).
.4
k(T)
,
(2):
� � =
(2)
–
(
−
����− ����
�� �
,
, ���� =
), T –
�
, �� .
. 4.
.
,
H2
D2
Er3+
f-
.Э
Yb3+. Э
. 5.
ё
4
11
I13/2
,
H2 .
~0.5
,
0.31
,
,
,
.
,
(
,
k(T))
2,0
Er 3+
4
I 9/2
4
I 11/2
я,
1,5
Э е
эВ
1,0
0,5
0,0
4
a)
F5/2
4
I 13/2
1.55 µ
0.98 µ
4
I 15/2
4
F7/2
non
rad
lum
pump
1.55 µ
F5/2
lum
0.98 µ
4
pump
F7/2
non
rad
4
I 15/2
Er3+
,
1.04 µ
pump
0.98 µ
.5Э
4
b)
I 13/2
1.04 µ
0.98 µ
Yb3+
D2
4
lum
lum
pump
Er 3+
4
I 9/2
4
I 11/2
Yb3+
H2
. 4.
Yb3+
a)
. 5 b). Э
(
b).
~0.72
,
4
2
F5/2
I13/2
.
0.47
.
0.09
,
–
,
,
. 4.
. 4,
,
,
(0.09
0.31
).
,
,
,
,
-
H2
D2 ,
80 – 120 K.
,
«
»
«
ё
»
.
,
12
.
ё
,
.
. 6.
7.
#2
808
1 – 4,
808
.
,
.
808
:
293
873 K.
. 6.
,
.
.
1420
825
.
808
.
,
1420
#3
1100
.
,
.
. 7
#2 (
)
808
.
,
825
900 K
.
1420
873
K.
13
660
,
825
20
60
273 K
873 K.
,
,
(
.8).
“ ”,
. 8 (a).
“ ”
1420
808
.
,
“ ”,
(
(К)
. 8b).
(Л)
:
0,55 эВ
1,54 эВ
(808
)
1,51 эВ
(825
)
1,54 эВ
(808
)
0,87 эВ
(1420
)
1,51 эВ
(825
)
.8
1,13 эВ
(1100
)
,
“A” (a)
“Б” (b).
,
1100
.
“
“ ”
.
”
,
“ ”
.
(
. 7)
,
,
825
,
,
1420
14
(
,
.
. 8).
,
.
#5, #6,
1420
#7
808
,
. 6.
1420
,
ё
,
ё
.
. 9.
#7, b) –
. a) –
, c) –
.
#7 (
,
9 a).
,
,
(
. 9 b #7).
~ 0.7
(
~ 2.6
,
.Э
15
. 9 c).
ё
(
. 10 b)
(
. 10 a).
. 10.
#5, b) .
: a), c) –
ё
,
#5-#7,
(
. 11 a).
,
,
,
,
k( )
( < 1) (
. 11
,
. 11 b).
(a)
#5,
 (b)
.
16
,
(
),
. Э
ё
#7
. 10 c).
(
,
«
»,
.
,
,
.
,
,
,
150 – 200 K.
.
1.
150
300 – 873 K.
,
,
,
2.
.
,
.
,
300
1420
873 K.
.
3.
.
.
17
,
з100 – 150 K,
H2
D2 .
4.
.
«
»
1420
300
873 K. Э
.
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19